Abstract
The mixed-spin Ising-Heisenberg and Heisenberg branched chains whose magnetic backbone consists of regularly alternating spins 1/2 and 5/2, the latter of which are additionally coupled to an extra spin 1/2 providing lateral branching, are investigated using exact analytical and density matrix renormalization group (DMRG) methods. The proposed spin-chain models capture some relevant aspects of the heterotrimetallic coordination polymer . The mixed spin- Ising-Heisenberg branched chain is exactly solvable under the assumption of an Ising-like exchange coupling along the chain, while the lateral branching is treated as an anisotropic Heisenberg exchange interaction. We determine the ground-state phase diagram and quantify a bipartite quantum entanglement between dimers at lateral branching. It is shown that the studied mixed-spin Ising-Heisenberg branched chain accurately fits available experimental data for temperature dependence of the magnetic susceptibility. The ground-state phase diagram of the analogous mixed spin- Heisenberg branched chain is obtained within the DMRG method. The ground-state phase diagrams of the Ising-Heisenberg and its full Heisenberg counterpart are contrasted. In particular, the ground-state phase diagram of the mixed-spin Heisenberg branched chain involves a special Gaussian critical point, for which a proper finite-size scaling analysis is provided to accurately estimate its location and the correlation length critical exponent.
1 More- Received 23 May 2020
- Revised 30 July 2020
- Accepted 4 August 2020
DOI:https://doi.org/10.1103/PhysRevB.102.064414
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