• Milestone

SrTiO3: An intrinsic quantum paraelectric below 4 K

K. A. Müller and H. Burkard
Phys. Rev. B 19, 3593 – Published 1 April 1979
An article within the collection: Physical Review B 50th Anniversary Milestones
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Abstract

The dielectric constants ε110 and their change with uniaxial 11¯0 stress in monodomain 001SrTiO3 samples have been measured as a function of temperature. Between 4 K and 0.3 K these quantities are independent of temperature. In one sample ε(T) was measured to 0.035 K and found to be constant. This proves the quantum-mechanical stabilization of the paraelectric phase below 4 K with a very high dielectric constant ε. The crossover from classical to quantum behavior on lowering the temperature is discussed, and it is shown that the coupling of the ferroelectric mode to acoustic ones is important. The ε(T) dependence is compared to earlier and recent theories. The former, yielding a coth (ΩkT) term, are found to be inadequate for the crossover region. A recent biquadratic ferroelectric mode-coupling theory fits the data better.

  • Received 19 July 1976

DOI:https://doi.org/10.1103/PhysRevB.19.3593

©1979 American Physical Society

Collections

This article appears in the following collection:

Physical Review B 50th Anniversary Milestones

These Milestone studies represent lasting contributions to physics by way of reporting significant discoveries, initiating new areas of research, or substantially enhancing the conceptual tools for making progress in the burgeoning field of condensed matter physics.

Authors & Affiliations

K. A. Müller

  • IBM Zürich Research Laboratory, 8803 Rüschlikon, Switzerland

H. Burkard*

  • Laboratory of Solid State Physics, ETH 8093 Zürich, Switzerland

  • *Present address: Brown Boveri & Cie., 5401 Baden, Switzerland.

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Issue

Vol. 19, Iss. 7 — 1 April 1979

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