Abstract
The nuclear and magnetic structures of have been investigated using neutron powder diffraction and Mössbauer spectroscopy at temperatures between 10 and 460 K. Fe and Mo atoms are found to order on alternate sites, as expected, giving rise to a double-perovskite-type unit cell. Upon cooling, a structural phase transition from cubic to tetragonal occurs at ∼400 K. In the tetragonal structure as the temperature decreases, the and octahedra rotate continuously around the c axis by an angle of up to ∼5.6°. In the phase, the magnetic moments for Fe and Mo order ferrimagnetically. The Fe magnetic spins first align along the c direction and then rotate to an angle of ∼54° with respect to the c axis; the refined Fe magnetic moment saturates at Mössbauer spectroscopy measurements show that the average valence of Fe is intermediate between the high spin configuration values of and The temperature dependence of the mean hyperfine field is in good agreement with the neutron-diffraction results and gives the same transition temperature.
- Received 10 November 1999
DOI:https://doi.org/10.1103/PhysRevB.62.14197
©2000 American Physical Society