Abstract
We investigated the electronic structure of to address the controversy regarding spin-orbit coupling (SOC) effects in metallic transition-metal oxides. Two issues have come to the forefront: (1) SOC effects on electronic structure and physical properties of and (2) the possible formation of a novel ground state in this material, the state. To better understand the SOC mechanism, we grew epitaxial films whose resistivity values were comparable with those of a single crystal. We obtained polarization-dependent optical and x-ray absorption spectra (XAS) and compared these results with those acquired using the generalized gradient approximation (GGA) and calculations. From the optical spectra, peak structures were identified at 0.4 and 2.0 eV, which could only be explained using the calculation. This suggests that SOC plays an important role in the electronic structure of . From the polarization-dependent XAS spectra, we observed that the empty state near the Fermi level lacks involvement of an Ir orbital. Despite the importance of SOC in , the state does not form in metallic .
- Received 4 November 2015
DOI:https://doi.org/10.1103/PhysRevB.93.045104
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