When a liquid drop contacts a wettable surface, the liquid spreads over the solid to minimize the total surface energy. The first moments of spreading tend to be rapid. For example, a millimeter-sized water droplet will wet an area having the same diameter as the drop within a millisecond. For perfectly wetting systems, this spreading is inertially dominated. Here we identify that even in the presence of a contact line, the initial wetting is dominated by inertia rather than viscosity. We find that the spreading radius follows a power-law scaling in time where the exponent depends on the equilibrium contact angle. We propose a model, consistent with the experimental results, in which the surface spreading is regulated by the generation of capillary waves.

• Received 22 February 2008

DOI:https://doi.org/10.1103/PhysRevLett.100.234501