Phase Diagram and Effective Shape of Semiflexible Colloidal Rods and Biopolymers

M. Dennison, M. Dijkstra, and R. van Roij
Phys. Rev. Lett. 106, 208302 – Published 20 May 2011
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Abstract

We study suspensions of semiflexible colloidal rods and biopolymers using an Onsager-type second-virial functional for a segmented-chain model. For mixtures of thin and thick fd virus particles, we calculate full phase diagrams, finding quantitative agreement with experimental observations. We show that flexibility, which renders the rods effectively shorter and thicker depending on the state point, is crucial to understanding the topologies of the phase diagrams. We also calculate the stretching of wormlike micelles in a host fd virus suspension, finding agreement with experiments.

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  • Received 27 December 2010

DOI:https://doi.org/10.1103/PhysRevLett.106.208302

© 2011 American Physical Society

Authors & Affiliations

M. Dennison1, M. Dijkstra1, and R. van Roij2

  • 1Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 5, 3584 CC Utrecht, The Netherlands
  • 2Institute for Theoretical Physics, Utrecht University, Leuvenlaan 4, 3584 CE Utrecht, The Netherlands

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Issue

Vol. 106, Iss. 20 — 20 May 2011

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