Abstract
The specific heat of is measured from 1 to 300 K. Below 50 K, is dominated by an Einstein term of energy , which represents 6.5% of the total lattice degrees of freedom. This concentration of phonon spectral weight at low energies is unusual in materials of cubic structure and is a possible indication of “rigid unit modes” discussed for underconstrained crystal structures. The relationship between and the large negative thermal expansion in this compound is discussed.
- Received 5 February 1998
DOI:https://doi.org/10.1103/PhysRevLett.80.4903
©1998 American Physical Society