Universal Nuclear Spin Relaxation and Long-Range Order in Nematics Strongly Confined in Mass Fractal Silica Gels

N. León, J.-P. Korb, I. Bonalde, and P. Levitz
Phys. Rev. Lett. 92, 195504 – Published 14 May 2004

Abstract

We show how the low-frequency dependence of the proton spin-lattice relaxation time T1(ν) of octylcyanobiphenyl liquid crystals confined in high-density silica gels evidences a long-range order nematic phase in spite of the strong confinement and random disorder of the gels. The universal value and frequency dependence observed, T1(ν)ν2/3, is interpreted within a relaxation model due to director fluctuations in nematic liquid crystals confined to mass fractal porous media. The model provides a relation T1(ν)ν2d/2, giving a reliable value of the structural fractal dimension df=2.67 for all the host silica gels.

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  • Received 21 December 2003

DOI:https://doi.org/10.1103/PhysRevLett.92.195504

©2004 American Physical Society

Authors & Affiliations

N. León1, J.-P. Korb2,*, I. Bonalde1, and P. Levitz2

  • 1Centro de Física, Instituto Venezolano de Investigaciones Científicas, Apartado 21874, Caracas 1020-A, Venezuela
  • 2Laboratoire de Physique de la Matière Condensée, UMR 7643 du CNRS, Ecole Polytechnique, 91128 Palaiseau Cedex, France

  • *Corresponding author. Email address: jean-pierre.korb@polytechnique.fr

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Vol. 92, Iss. 19 — 14 May 2004

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