Abstract
Five-membered hypervalent iodine heterocycles derived from benziodoxole and benziodazole oxide have recently emerged as reagents of choice for various synthetically useful oxidative transformations. In particular, IBX (2-iodoxybenzoic acid) and DMP (Dess-Martin periodinane) are widely used for the selective oxidation of primary and secondary alcohols and for a variety of other important oxidations. IBX-amides and IBX-esters are a new class of pentavalent iodine reagents with a pseudo-benziodoxole structure and a reactivity pattern similar to IBX.
Keywords: hypervalent iodine, oxidation, benziodoxole, benziodazole, ibx, dmp
Current Organic Synthesis
Title: Benziodoxole-Based Hypervalent Iodine Reagents in Organic Synthesis
Volume: 2 Issue: 1
Author(s): Viktor V. Zhdankin
Affiliation:
Keywords: hypervalent iodine, oxidation, benziodoxole, benziodazole, ibx, dmp
Abstract: Five-membered hypervalent iodine heterocycles derived from benziodoxole and benziodazole oxide have recently emerged as reagents of choice for various synthetically useful oxidative transformations. In particular, IBX (2-iodoxybenzoic acid) and DMP (Dess-Martin periodinane) are widely used for the selective oxidation of primary and secondary alcohols and for a variety of other important oxidations. IBX-amides and IBX-esters are a new class of pentavalent iodine reagents with a pseudo-benziodoxole structure and a reactivity pattern similar to IBX.
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Cite this article as:
Zhdankin V. Viktor, Benziodoxole-Based Hypervalent Iodine Reagents in Organic Synthesis, Current Organic Synthesis 2005; 2 (1) . https://dx.doi.org/10.2174/1570179052996982
DOI https://dx.doi.org/10.2174/1570179052996982 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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