doiSerbia

Analytical methods for arsenic speciation analysis

Rajaković Ljubinka V. (Faculty of Technology and Metallurgy, Belgrade)
Todorović Žaklina N. (Vinča Institute of Nuclear Sciences, Belgrade)
Rajaković-Ognjanović Vladana N. (Faculty of Civil Engineering, Belgrade)
Onjia Antonije E. (Vinča Institute of Nuclear Sciences, Belgrade)

Arsenic exists in the form of various chemical species differing by their physicochemical behavior, in toxicity, bioavailability and biotransformation. The determination of arsenic species is an important issue for environmental, clinical and food chemistry. However, differentiation of these species is a quite complex analytical task. Numerous speciation procedures have been studied that include electrochemical, chromatographic, spectrometric and hyphenated techniques. This review comprehends the relevant research in the field of arsenic speciation analysis with novel applications and significant advances. Stability of arsenic species and each of the analytical steps (sample collection, storage, preservation, extraction) of the arsenic speciation methods was particularly evaluated. Analytical validation and performance of these methods are also reviewed.

Keywords: arsenic speciation, adsorption, extractions, water, soil, biological sample