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Journal of the Serbian Chemical Society 2014 Volume 79, Issue 6, Pages: 719-727
https://doi.org/10.2298/JSC130818133S
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Physical properties of aqueous solutions of potassium carbonate + glycine as a solvent for carbon dioxide removal

Shuaib Shaikh Muhammad (Research Center for CO Capture (RCCOC), Department of Chemical Engineering, Universiti Teknologi PETRONAS, Tronoh, Perak, Malaysia)
Shariff Azmi M. (Research Center for CO Capture (RCCOC), Department of Chemical Engineering, Universiti Teknologi PETRONAS, Tronoh, Perak, Malaysia)
Bustam Mohd A. (Research Center for CO Capture (RCCOC), Department of Chemical Engineering, Universiti Teknologi PETRONAS, Tronoh, Perak, Malaysia)
Murshid Ghulam (Research Center for CO Capture (RCCOC), Department of Chemical Engineering, Universiti Teknologi PETRONAS, Tronoh, Perak, Malaysia)

The physical properties such as densities, viscosities, and refractive indices of aqueous solutions of potassium carbonate (PC) blended with glycine (Gly) as solvent blends for CO2 capture were measured. The properties were measured at ten different temperatures from (298.15 to 343.15) K. The mass fractions (w1 + w2) % of the (PC + Gly) blends were (0.05 + 0.01, 0.10 + 0.02, 0.15 + 0.03, 0.20 + 0.04, 0.25 + 0.05, 0.30 + 0.06, 0.35 + 0.07, and 0.40 + 0.08), respectively. The analysis of experimental results shows that, the densities, viscosities, and refractive indices of the aqueous (PC + Gly) blend increase with increasing the concentration of the potassium carbonate and glycine, and decrease with decreasing the temperature. The experimental data of density, viscosity and refractive index were correlated by a least-squares method as a function of temperature. The predicted data were estimated from coefficients of correlation equations for all measured properties, and reported with standard deviation (SD). The experimental data are in consistent with the predicted data.

Keywords: density, viscosity, refractive index, potassium carbonate, glycine, CO2 capture