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Article

Preparation and Characterization of High Thermal Conductivity and Low CTE Polyimide Composite Reinforced with Diamond Nanoparticles/SiC Whiskers for 3D IC Interposer RDL Dielectric

1
National Key Laboratory of Science and Technology on Micro/Nano Fabrication, School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
2
School of Electronic and Electrical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
*
Author to whom correspondence should be addressed.
Submission received: 27 March 2019 / Revised: 5 May 2019 / Accepted: 8 May 2019 / Published: 13 May 2019
(This article belongs to the Special Issue Advances in Polyimide Films: Preparation, Properties and Applications)

Abstract

:
Low thermal conductivity and large coefficient of thermal expansion (CTE) are the most serious disadvantages of the polymer dielectric for the interposer redistribution layer (RDL). In this paper, a high thermal conductivity and low CTE composite with polyimide (PI) matrix and diamond nanoparticles/SiC whiskers reinforcement is proposed. The preparation and characterization of the composite film are presented and the effects of the composite on the improvement of the interposer properties are investigated. With 10 wt% diamond-nanoparticles and 7 wt% SiC-whiskers, the composite film has a thermal conductivity of 1.63 W/m·K and a CTE of 16.7 ppm/°C (compared with 0.19 W/m·K and 55.6 ppm/°C of the PI). Interposers with PI RDL dielectric and the composite RDL dielectric are fabricated, respectively. The simulation result shows that the composite dielectric can significantly enhance the properties of the interposer compared with the PI dielectric. The thermal resistance of the interposer decreases from 8.04 °C/W to 1.15 °C/W. The maximum von Mises stress decreases from 72.8 MPa to 16.9 MPa and the warpage decreases from 1.13 μm to 0.15 μm. Thermal distribution tests are performed as well. The results show that the maximum temperature of the interposer decreases from 64 °C to 45.1 °C. The composite developed in this study can reduce the temperature and enhance the reliability of the chips with interposers. It has the potential to expand the application of the interposers in high thermal density integration and high reliability devices.

1. Introduction

Development of the 3D integrated circuit (IC) integration is driven by the demands for further miniaturization of device, higher integration density, lower power consumption and better performance [1,2,3,4]. Si interposer technology is one of the promising solutions for the 3D IC integration which is usually used to stack active chips on a passive Si interposer with through silicon vias (TSVs) as shown in Figure 1a [5,6]. The horizontal electrical interconnection between chips and chips, chips and TSVs is realized through the redistribution layer (RDL) which incorporates multilevel routing layers and dielectric layers [7].
Depending on the material, the RDL dielectrics can be divided mainly into two categories: deposited inorganic dielectrics and spin-coated polymer dielectrics. The deposited inorganic dielectrics include SiO2, Si3N4, AlN, etc. and the spin-coated polymer dielectrics include Polyimide (PI), Benzocyclobutene (BCB), Poly arylene ether, SiLK, Polysiloxane and so on [8,9,10]. Spin-coated polymer dielectrics are widely used in 3D IC integration for the advantages of low cost, low relative permittivity (leading to low parasitic capacitance and low resistance-capacitance delay) and the convenience in planarization (especially for multilevel metallization). However, there are several disadvantages for the use of the polymer as RDL dielectric. One serious drawback is its poor thermal conductivity that works as a thermal barrier to heat flow. As the integration density increases, more localized heat is produced and reliability problems become critical. The low thermal conductivity of the polymer dielectric aggravates these problems related to thermal concentration and thermal stress [11,12]. It is worth noting that, although the dielectric layer occupies only a small fraction of the Si interposer in thickness, it provides the majority of the thermal resistance through the heat conduction path (Rinterposer = Rrdl + Rsub//TSV, as illustrated in Figure 1b). According to the study presented by Pinel et al. [13], the 3 μm thick polymer dielectric film of the chip has a thermal resistance (2.31 °C/W) four times larger than that of the Si substrate of 500 μm thick (0.46 °C/W). This indicates that more than 80% of the thermal resistance is provided by the polymer dielectric in this polymer dielectric/Si substrate structure. Thus, improving the thermal conductivity of the polymer dielectric is crucial to the heat dispassion of Si interposer. Another disadvantage of the polymer dielectric is its large coefficient of thermal expansion (CTE) (e.g., PI: ~30–60 ppm/°C) compared with the interposer substrate (Si: 2.6 ppm/°C) and routing layer (Cu: 17 ppm/°C) [9]. The CTE mismatch among RDL dielectric, substrate and routing layer intensifies the thermal stress in the 3D integration [14,15]. Therefore, spin-coated polymer-based dielectrics with high thermal conductivity and low CTE has very good application prospects in the 3D IC integration.
At present, there are many studies focusing on improving the thermal conductivity of polymer by adding in high thermal conductivity particles (also lead to a drop in the CTE due to the low CTE of the particles) [16,17,18,19,20,21,22,23,24]. Xu et al. proposed a BCB-carbon nanotube (CNT) composite as a bonding interface material [16]. An 80% improvement in thermal conductivity is achieved with the CNT concentration at 1.5 wt%. Anri et al. developed a novel polymer composite as thermal interface material with silicone matrix and fillers of diamond and hexagonal boron nitride platelets [17]. The composite has a maximum thermal conductivity of 6.1 W/m·K with the filler concentration at 90 wt%. Xie et al. presented a PI/AlN composite with an enhanced thermal conductivity of 0.8 W/m·K compared with 0.22 W/m·K of PI [18]. From these studies, it can be concluded that the thermal conductivity of the polymer can be significantly improved by adding in high thermal conductivity particles. However, the composites presented in these studies are mainly developed for bonding interface, thermal interface, surface coating or electrical packaging, most of which are not suitable to be used as RDL dielectric. For example, in Xu’s research, the insulation property of the composite is impaired by the CNT fillers, which will induce a large leakage current when the composite is used as RDL dielectric. For the composite developed by Anri, the size of the diamond particles (more than 9 μm) is too large for the thin dielectric layer and the viscosity of the composite is too high for spin-coating process (due to the high filler concentration). As presented by Xie, the addition of AlN particles improves the thermal conductivity of the composite, but it also increases the relative permittivity significantly which may cause severe signal delay problems. Thus, besides the enhancement of thermal conductivity and the reduction of CTE, it is essential for the composite to maintain its electrical and mechanical properties to be used as spin-coating dielectric, such as good insulation property, low relative permittivity, good fluidity for spin-coating and enough mechanical strength.
In this paper, the preparation and characterization of a composite with high thermal conductivity and low CTE is presented and its application in interposer RDL dielectrics is discussed as well. The PI is chosen as the matrix for its excellent properties including high elongation at break, good thermal and chemical stability, low relative permittivity and good insulating property [25]. Diamond nanoparticle (DN) and silicon carbide whisker (SCW) are used as reinforcement materials. The DN is chosen for its high thermal conductivity, relatively low electric constant and high resistivity [17,26]. The SCW is selected for its better thermal and chemical stability, higher strength, higher elastic modulus and better abrasion resistance compared with other whiskers [27,28]. The DNs and SCWs are dispersed into the matrix to form particle-whisker network structures for improving the thermal conductivity, reducing the CTE and reinforcing the mechanical strength of the matrix.

2. Preparation

The polyamic acid (PAA), as the precursor of PI, was purchased from the Pome Sci tech Co., Ltd., Beijing, China. This PAA product (ZKPI-305) was of PMDA-ODA type. The chemical structure and the preparation process of the PMDA-ODA type PAA/PI have been extensively studied in previous literature [22,29,30]. The N-methyl pyrrolidone (NMP), in which the nanoparticles were pre-dispersed, was obtained from Xuntu Chemical Co., Ltd., Shanghai, China. The DNs were obtained from the Sino-Crystal Micro-Diamond Co., Ltd., Zhengzhou, China, with an average particle size of 50 nm. The SCWs were produced by Sinet Advanced Materials Co. Ltd., Changsha, China, with an average diameter of 300 nm and lengths ranging from 10 to 50 μm.
Ball-milling and mechanical stirring experiments were performed to mix the DNs, SCWs and PI coating resin. The result showed that the reinforcement materials were not well dispersed in the matrix when directly mixed together, which might be due to the high viscosity of the PI resin. Figure 2a shows the dispersion result of a direct mixture process (8 h ball-milling followed by 4 h mechanical stirring). It can be seen that some SCWs were tangled up to form whisker clusters. Furthermore, the SCWs were prone to break off during the ball-milling process, leading to degradation in the enhancement effect. Thus, for the preparation of the composite film, it was a challenge to disperse these two different reinforcement materials in the matrix with uniform distribution.
After a large number of experiments, a mixing method was developed with a good dispersion result. Whiskers and particles are randomly distributed in the matrix as shown in Figure 2b. In this method, the reinforcement materials were pre-dispersed respectively before mixing with PI. The DNs were pre-dispersed in the NMP by ball-milling before mixing with PI. Since the SCWs were not suitable for ball-milling, they were pre-dispersed by a mechanical stirring process in ethanol. The ethanol was chosen as the pre-dispersing matrix for its low viscosity and high volatility. The low viscosity was beneficial for the pre-dispersion of SCWs, and the high volatility was necessary for the subsequent mixing process with PI. Since the ethanol was easy to volatilize during the mixing process, the mixture becomes viscous again to suppress the sedimentation and stratification of the fillers.
The preparation process of the composite film is illustrated in Figure 3. The details are described as follows.
(1)
The DNs were mixed with the NMP. Then the mixture was ball-milled for 2 h with a rotation rate of 500 r/min;
(2)
The PI precursor was added into the mixture and then was ball-milled for another 8 h to fully disperse the nanoparticles in the PI matrix;
(3)
The SCWs were added into the ethanol at a mass ratio of 1:20 and then mechanically stirred for 1 h with a rotation rate of 900 r/min. The vessel was sealed during the stirring process to avoid the volatilization of the ethanol;
(4)
The ball-milled DN/PI mixture was added into the SiC/ethanol mixture. Then it was treated with ultrasonication and mechanical stirring alternately. During this process, the vessel was open and the ethanol continued to volatilize. This process took about several hours until most of the ethanol was volatilized and the mixture became viscous;
(5)
The DN/SCW/PI composite was placed in vacuum for 20 min to remove the air from the mixture;
(6)
The composite was spin-coated on the silicon wafer;
(7)
The wafer was placed in an oven with nitrogen atmosphere and the DN/SCW/PI precursor was cured through a stepped heating process (the same process as curing the PI matrix). The temperature curve is shown in Figure 4.
Scanning electron microscopy (SEM) was used to observe the morphology of the composite film. The surface and cross sectional SEM images of the composite film are shown in Figure 5. It can be seen from the images that the DNs and the SCWs were uniformly distributed in the PI matrix and the nanoparticle-whisker network structures were formed. The nanoparticle-whisker network structures can enhance the mechanical strength and improve the thermal conductivity of the composite effectively [17,28].

3. Characterization

A series of tests was carried out to evaluate the performance of this composite as an RDL dielectric including thermal conductivity, CTE, tensile modulus and tensile strength, relative permittivity, insulating property and so on. The mass fractions of the SCWs (in the precursor) of the composite test samples were fixed at 7 wt% and the mass fraction of the DNs (in the precursor) were 0 wt%, 1 wt%, 2.5 wt%, 5 wt%, 7.5 wt% and 10 wt%, respectively. According to our early research on the SCW/PI composite [14], good mechanical properties and the highest thermal conductivity of the composite was obtained when the concentration of SCWs was about 7 wt%. Concentrations higher than 7 wt% would result in a decrease in the performance of the SCW/PI composite due to the agglomeration of the whiskers. Instead of adding more SCWs, the addition of an appropriate amount of DNs would further increase the thermal conductivity of the composite without causing agglomeration problems. The highest mass fraction of the DNs was 10 wt%, since more DNs would make the precursor too viscous for the spin-coating process. Moreover, high mass fractions of the inorganic additives make the composite too fragile to be used as RDL dielectric.

3.1. Thermal Conductivity

The thermal conductivity of the composite film was calculated according to Equation (1):
k = α ρ c
where α, ρ and c were the thermal diffusivity, density and specific heat of the film, respectively.
The thermal diffusivity of the film was measured by the laser flash method (LFA 467 HyperFlash, Netzsch) at room temperature of 25 °C. The density was obtained from the immersion method and the specific heat was measured by the differential scan calorimeter (DSC 204F1, Netzsch). The thermal conductivity of the composite film versus different DNs concentrations is shown in Figure 6. As the concentration of the DNs increased, the thermal conductivity of the composite increased accordingly. This indicates that the reinforcement materials were well dispersed in the composite with 10 wt% DNs and 7 wt% SCWs. Otherwise, there would have been a decrease in the thermal conductivity caused by the agglomeration. The composite had an excellent thermal conductivity of 1.63 W/m·K with 10 wt% DNs and 7 wt% SCWs, when the thermal conductivity of the PI without reinforcement materials was only 0.19 W/m·K.

3.2. CTE

The CTE of the composite was measured by the dilatometer (DIL 402, Netzsch). As shown in Figure 7, the CTE (at room temperature of 25 °C) of PI decreased from 55.6 ppm/°C to 25.6 ppm/°C after the addition of 7 wt% SCWs. It continued to decrease from 25.6 ppm/°C to 16.7 ppm/°C as the concentration of DNs increased from 0 wt% to 10 wt%. The decrease of the CTE could be attributed to two factors. Firstly, the addition of DNs and SCWs which have low CTE reduced the total CTE of the composite. Secondly, the expansion or contraction of the matrix was restrained effectively by the particle-whisker network structures due to their strong interaction.

3.3. Other Properties

As discussed before, besides the enhancement of thermal conductivity and the reduction of CTE, it is essential for the composite to maintain its electrical and mechanical properties to be used as spin-coating dielectrics. The dielectric property, insulation property and mechanical strength of the composite with the optimized component ratio were tested and the results are shown in Table 1. The corresponding properties of the PI matrix are also listed for comparison. The mechanical strength of the PI matrix was enhanced by the reinforcement materials. The tensile strength increased from 81 MPa to 145 MPa and the Young’s modulus increased from 2.5 GPa to 8.4 GPa, at the cost of the reduction of elongation at break from 7.2% to 3.3%. Affected by the poor dielectric properties of the reinforcement materials, the relative permittivity of the composite increased to 4.6 compared with that of the PI matrix of 3.5 at 1 MHz. The addition of SiC which has a relatively low resistivity made the volume resistivity decrease from 4.3 × 107 Ω·cm to 2.1 × 107 Ω·cm. Although the elongation at break, dielectric property and insulation property were degraded to some degree, the degradation is still acceptable.

4. Application as Interposer RDL Dielectric

To verify the feasibility of the composite to be used as interposer RDL dielectric, interposer test samples were fabricated. Moreover, to evaluate the effects of the composite on the improvement of interposer properties, thermal–mechanical simulations and thermal distribution tests were performed.
The fabrication process of the interposer RDL is shown in Figure 8. The routing layers were fabricated by Cu electroplating and the dielectrics were formed by spin-coating. It is worth noting that the PI matrix was no longer patternable due to the insoluble reinforcement materials. Thus, holes (openings in the dielectric to connect the adjacent routing layers) could not be formed by patterning. An electroplating-coating-polishing process was developed for the connection of the adjacent routing layers. First, connecting pillars were fabricated on the lower routing layer. Then the composite was spin-coated to cover the routing layer and the connecting pillars. At last, a polishing process was performed to reveal the connecting pillars for the connection with the upper routing layer.
Interposer samples with both PI dielectric and the composite dielectric (10 wt% DNs and 7 wt% SCWs) were fabricated, as shown in Figure 9. Cu routing layers, substrates and TSVs of the two samples were exactly the same. TSVs were arranged on the periphery of the interposer and two Cu routing layers were fabricated on the front side. It can be seen that, the DN/SCW/PI composite dielectric is opaque, unlike the transparent PI dielectric. The specifications for the components of the interposer are listed in Table 2.
Finite element analyses (FEA) were performed to investigate the temperature distribution, von Mises stress distribution and the warpage of the two different interposers. Comparisons were made to evaluate the effects of the composite dielectric on the properties enhancement of the interposer. In the simulation model, a heating chip with a power density of 20 W/cm2 was assembled on the interposer. The heat was supposed to dissipate from the backside of the interposer which was set to be at the environment temperature of 17 °C. The thermal convection and radiation were neglected in the simulation, since the die surface in a real packaged chip is always covered with a thick layer of protecting polymer which hinders the thermal convection and radiation.
As shown in Figure 10, the DN/SCW/PI composite RDL dielectric significantly enhanced the thermal–mechanical properties of the interposer compared with the PI dielectric. The maximum temperature of the interposer could be reduced from 47 °C to 26.8 °C and the temperature difference (Tmax – Tmin) decreased from 20 °C to 9.8 °C, mainly due to the significant increase of the thermal conductivity of the dielectric material. The maximum von Mises stress decreased from 72.8 MPa to 16.9 MPa and the warpage decreased from 1.13 μm to 0.15 μm. These two improvements could be attributed to three factors, the reduction of the thermal gradient, the reduction of the CTE and the increase of the Young’s modulus of the dielectric [15]. From the heat flow and the temperature of both sides of the interposer, the thermal resistances of the interposers can be calculated, which were 8.04 °C/W (PI dielectric) and 1.15 °C/W (the composite dielectric), respectively.
The thermal distributions of the interposers with different RDL dielectrics were also investigated by experiments. A heating chip with a power density of 20 W/cm2 was attached to the interposer by thermal grease and the interposer was attached to a metal heat sink. The thermal distributions were recorded by an infrared camera. As shown in Figure 11, the maximum temperature of the interposer with the composite dielectric was 45.1 °C and that of the interposer with PI dielectric was 64 °C. The temperature differences of the interposers were 46.6 °C and 26.8 °C, respectively. The experimental values were greater than the simulated results, which could be attributed to the high thermal resistance of the thermal grease (leading to an extra interface thermal resistance). However, the experimental result proved that the DN/SCW/PI composite is very effective in the enhancement of the thermal property of the interposer. Figure 11 also shows that the Cu routing layer had an obvious temperature difference with the PI dielectric, which may cause stress concentration and lead to reliability issues. However, in the DN/SCW/PI composite dielectric, the temperature of the Cu routing layer was almost the same as that of the dielectric, benefiting from the surrounding high thermal conductivity composite.

5. Conclusions

In this paper, a high thermal conductivity and low CTE composite with PI matrix and DN/SCW reinforcement is proposed. A preparation method of the composite film is developed, in which the two reinforcement materials are pre-dispersed respectively. By this preparation method, a good dispersion result can be obtained and the whiskers and particles are randomly distributed in the matrix.
A series of tests are carried out to evaluate the performance of this composite film. The thermal conductivity and the CTE of the composite film are tested when the mass fraction of the SCWs is fixed at 7 wt% and the mass fraction of the DNs is 0 wt%, 1 wt%, 2.5 wt%, 5 wt%, 7.5 wt% and 10 wt%, respectively. As the concentration of the DNs increases, the thermal conductivity increases and the CTE decreases. When the concentrations of the DNs and SCWs are 7 wt% and 10 wt% respectively, the composite film has the maximum thermal conductivity of 1.63 W/m·K and the minimum CTE of 16.7 ppm/°C (compared with 0.19 W/m·K and 55.6 ppm/°C of PI). The dielectric property, insulation property and mechanical strength of the composite film are also tested with the optimized component ratio. The results show that the electrical and mechanical properties of the composite are eligible for spin-coating dielectric, although some properties are degraded to some degree, at the cost of the improvement of thermal conductivity and CTE.
Interposer test samples are fabricated and the effects of the composite on the improvement of the interposer properties are investigated. Simulations by FEA are performed and the results indicate that the DN/SCW/PI composite used as an RDL dielectric has significantly enhanced the thermal–mechanical properties of the interposer compared with the PI dielectric. The thermal resistances of the interposer decreases from 8.04 °C/W to 1.15 °C/W and the temperature difference decreases from 20 °C to 9.8 °C. The maximum von Mises stress decreases from 72.8 MPa to 16.9 MPa and the warpage decreases from 1.13 μm to 0.15 μm.
The thermal distributions of the interposers with different RDL dielectrics are also investigated by experiments. The result shows that, compared with the PI dielectric, the composite dielectric can reduce the maximum temperature of the interposer from 64 °C to 45.1 °C, the temperature difference from 46.6 °C and 26.8 °C.
The composite can significantly reduce the temperature and enhance the reliability of the interposer chips. As a matter of experience, for every 10 °C increase in the junction temperature, the lifetime of the chip will be reduced by about half [31]. Thus, the composite can extend the lifetime of the interposer chips as well. In conclusion, the composite developed in this study can enhance the properties of the interposer chips and has the potential to expand the application of the interposers, especially in high thermal density integration and high reliability devices.

Author Contributions

Conceptualization, G.D. and J.L.; methodology, J.L. and Y.S.; software, Y.W. and J.L.; validation, X.Z., G.D.; formal analysis, J.L. and Y.W.; investigation, Y.L. and G.W.; resources, G.D.; data curation, J.L.; writing—original draft preparation, J.L.; writing—review and editing, Y.S. and G.W.; visualization, Y.W.; supervision, X.Z.; project administration, G.D.; funding acquisition, G.D.

Funding

This research was funded by China Postdoctoral Science Foundation (2018M630440).

Acknowledgments

The authors would like to thank supports from the Shanghai Professional Technical Service Platform for Non-Silicon Micro-Nano Integrated Manufacturing.

Conflicts of Interest

The authors declare no conflict of interest.

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Figure 1. (a) Si interposer integration and (b) its heat conduction path.
Figure 1. (a) Si interposer integration and (b) its heat conduction path.
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Figure 2. The diamond nanoparticle (DN)/ silicon carbide whisker (SCW)/ polyimide (PI) composite films prepared by (a) direct mixture process and (b) the pre-dispersion method.
Figure 2. The diamond nanoparticle (DN)/ silicon carbide whisker (SCW)/ polyimide (PI) composite films prepared by (a) direct mixture process and (b) the pre-dispersion method.
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Figure 3. The preparation process of the composite film.
Figure 3. The preparation process of the composite film.
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Figure 4. The stepped heating process for curing the composite or PI precursor.
Figure 4. The stepped heating process for curing the composite or PI precursor.
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Figure 5. The surface (a) and cross sectional (b) scanning electron microscopy (SEM) images of the composite film.
Figure 5. The surface (a) and cross sectional (b) scanning electron microscopy (SEM) images of the composite film.
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Figure 6. Thermal conductivity of the composite versus different DN concentrations.
Figure 6. Thermal conductivity of the composite versus different DN concentrations.
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Figure 7. Coefficient of thermal expansion (CTE) of the composite versus different DN concentrations.
Figure 7. Coefficient of thermal expansion (CTE) of the composite versus different DN concentrations.
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Figure 8. The fabrication process of the interposer redistribution layer (RDL).
Figure 8. The fabrication process of the interposer redistribution layer (RDL).
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Figure 9. (a) Interposer sample with PI dielectric and (b) interposer sample with the composite dielectric.
Figure 9. (a) Interposer sample with PI dielectric and (b) interposer sample with the composite dielectric.
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Figure 10. The thermal distribution, von Mises stress and warpage of the interposers with (a) PI dielectric and (b) the proposed composite dielectric.
Figure 10. The thermal distribution, von Mises stress and warpage of the interposers with (a) PI dielectric and (b) the proposed composite dielectric.
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Figure 11. (a) The thermal distribution test sample. (b) Thermal distribution of the interposer with PI dielectric. (c) Thermal distribution of the interposer with the proposed composite dielectric.
Figure 11. (a) The thermal distribution test sample. (b) Thermal distribution of the interposer with PI dielectric. (c) Thermal distribution of the interposer with the proposed composite dielectric.
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Table 1. The properties of the composite (10 wt% DNs, 7 wt% SCWs) compared with the PI matrix.
Table 1. The properties of the composite (10 wt% DNs, 7 wt% SCWs) compared with the PI matrix.
Thermal Conductivity
(W/m·K)
Coefficient of Thermal Expansion
(ppm/°C)
Tensile Strength
(MPa)
Young’s Modulus
(GPa)
Elongation at Break
(%)
Relative Permittivity at 1 MHzVolume Resistivity at 1 MHz
(Ω·cm)
PI0.1955.6812.57.23.54.3 × 107
DN/S-CW/PI1.6316.71458.43.34.62.1 × 107
Table 2. Specifications for all components of the interposer test sample.
Table 2. Specifications for all components of the interposer test sample.
ComponentsMaterialsDimensions
Interposer substrateSiLength = 10 mm, Width = 10 mm, Thickness = 0.2 mm
TSVCuRadius = 40 μm, Height = 200 μm
RDL routing layerCuThickness = 6 μm, Width = 60 μm, Line space = 60 μm
RDL dielectricPI/CompositeThickness = 6 μm

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MDPI and ACS Style

Luo, J.; Wu, Y.; Sun, Y.; Wang, G.; Liu, Y.; Zhao, X.; Ding, G. Preparation and Characterization of High Thermal Conductivity and Low CTE Polyimide Composite Reinforced with Diamond Nanoparticles/SiC Whiskers for 3D IC Interposer RDL Dielectric. Appl. Sci. 2019, 9, 1962. https://0-doi-org.brum.beds.ac.uk/10.3390/app9091962

AMA Style

Luo J, Wu Y, Sun Y, Wang G, Liu Y, Zhao X, Ding G. Preparation and Characterization of High Thermal Conductivity and Low CTE Polyimide Composite Reinforced with Diamond Nanoparticles/SiC Whiskers for 3D IC Interposer RDL Dielectric. Applied Sciences. 2019; 9(9):1962. https://0-doi-org.brum.beds.ac.uk/10.3390/app9091962

Chicago/Turabian Style

Luo, Jiangbo, Yongpeng Wu, Yunna Sun, Guilian Wang, Yanmei Liu, Xiaolin Zhao, and Guifu Ding. 2019. "Preparation and Characterization of High Thermal Conductivity and Low CTE Polyimide Composite Reinforced with Diamond Nanoparticles/SiC Whiskers for 3D IC Interposer RDL Dielectric" Applied Sciences 9, no. 9: 1962. https://0-doi-org.brum.beds.ac.uk/10.3390/app9091962

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