Analysis of Corn Straw Pyrolysis Bio-Oil Composition

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Abstract:

The fast pyrolysis of corn straw in the fluidized bed reactor to produce bio-oil, the preliminary qualitative research on the composition of the bio-oil was analyzed by GC-MS to provide the basis for their purification, refining and long-term stability studies. The result shows that: the bio-oil producted by corn straw pyrolysis contains 66 components, mainly containing phenol, furan, acetic acid, propanoic acid, ethanone, vanillin, aldehyde, bio-oil water content is 33% and pH is 3.1, which has a great significance to improve the quality of bio-oil.

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14-19

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March 2015

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[1] Corma A, Huber GW, Sauvanaud L, O'Connor P: Processing biomass-derived oxygenates in the oil refinery: catalytic cracking (FCC) reaction pathways and role of catalyst. J Catal (2007), 247: 307-327.

DOI: 10.1016/j.jcat.2007.01.023

Google Scholar

[2] Huber GW, Iborra S, Corma A: Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. Chem Rev (2006), 106: 4044-4098.

DOI: 10.1021/cr068360d

Google Scholar

[3] Simonetti DA, Dumesic JA: Catalytic production of liquid fuels from biomass-derived oxygenated hydrocarbons: catalytic coupling at multiple length scales. Catal Rev (2009), 51: 441-484.

DOI: 10.1080/01614940903050626

Google Scholar

[4] Seung-Soo Kim, Sung Hoon Park, Jong-Ki Jeon, Daejun Chang, Sang Chai Kim, Kyong-Hwan Lee, Young-Kwon Park: Catalytic pyrolysis of waste wood chip over mesoporous materials using Py-GC/MS, Res Chem Intermed (2011), 37: 1355-1361.

DOI: 10.1007/s11164-011-0396-6

Google Scholar

[5] Agblevor F A, Besler S: Effect on the quality of fast pyrolysis oils, Energy fuels (1996), 10(2): 293-298.

DOI: 10.1021/ef950202u

Google Scholar

[6] Wang Lihong, Bai Xueyuan, Yi Weiming, et al: Characteristics of bio-oil from plasma heated fluidized bed pyrolysis of corn stalk, Transactions of the Chinese Society of Agricultural Engineering (2006), 22(3): 108-111.

Google Scholar

[7] Brandon Jeffrey, Dan Nettleton, Najeeb Kuzhiyil, Marjorie Rover, Robert C. Brown, Kendall Lamkey, Thomas Lübberstedt: Significant Variation for Bio-oil Compounds After Pyrolysis/Gas Chromatography–Mass Spectrometry of Cobs and Stover Among Five Near-Isogenic Brown Midrib Hybrids in Maize, Bioenerg. Res (2013).

DOI: 10.1007/s12155-013-9395-3

Google Scholar

[8] Xianwei Zheng, Yan Fu, Jie Chang, Shengyou Liang: Classified Separation of Flash Pyrolysis Oil, Bioenerg. Res (2013), 6: 1165-1172.

DOI: 10.1007/s12155-013-9298-3

Google Scholar

[9] Liu Shanjian, Yi Weiming, Bai Xueyuan, et al: Experimental study on biomass fast pyrolysis in fluidized bed and analysis of bio-oil, Transactions of the CSAE (2009), 25(1): 203-207.

Google Scholar

[10] Chang Sheng, Zhao Zeng. 1i, Zhang Wei, Zheng An. qing et al: Analysis of structure comparison of different bio-oil chemical composition, Journal of Fuel Chemistry and Technology (2011), 39 (10): 746-753.

Google Scholar

[11] Wei Lihong, Yin Na, Li Rundong, et al: The super fine dry sludge and coal mixed firing characteristics, Journal of Shenyang Aerospace University (2009), 26(5): 68-73.

Google Scholar

[12] Cai Wenjuan, Liu Yaoxin, Yang Tianhua, Li Rundongl: The bio-oil from biomass pyrolysis GC-MS analysis, Journal of Shenyang Aerospace University (2010), 27(3): 71-75.

Google Scholar

[13] Wu Yiming: Plant fiber chemistry, Beijing: China Light Industry Press (1991).

Google Scholar