Thermal Analysis and Surface Morphology Study of Cholesterol: Β-Cyclodextrin Inclusion Complex

Article Preview

Abstract:

nclusion complex of cholesterol:β-cyclodextrin (CβIC) was characterized for thermal analysis by differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The difference of endothermic peak between inclusion compounds of cholesterol:β-cyclodextrin (CβIC) with pure cholesterol and β-cyclodextrin endothermic peaks confirmed the formation of inclusion complex. SEM results showed that of cholesterol:β-cyclodextrin inclusion complex (CβIC) observed in the form of irregular crystalline particles which has different morphology from CHO and βCD. The results obtained from this study will able to give valuable information about cholesterol-reduced egg yolk properties that could be useful to produce healthy-egg yolk based products.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

221-225

Citation:

Online since:

September 2013

Export:

Price:

[1] C. D. Santos, M. P. Buera, & M. F. Mazzobre, Phase solubility studies and stability of cholesterol/β-cyclodextrin inclusion complexes, J Sci Food Agric. 91 (2010) 2551-255.

DOI: 10.1002/jsfa.4425

Google Scholar

[2] L. Szente, & J. Szejtli, Cyclodextrins as food ingredients, Trends in Food Science & Technology. 15 (2004) 137–142

DOI: 10.1016/j.tifs.2003.09.019

Google Scholar

[3] A. H. Zaibunnisa, S. Norashikin, S. Mamot, M. I. Rosli, A. W. M. Wan, H. Osman, Characterization of cyclodextrin complexes with turmeric oleoresin. Food chemistry, 114 (2009) 459-465.

Google Scholar

[4] G. Astray, C. Gonzalez-Barreiro, J. C. Mejuto, R. Rial-Otero, J. S. Ga´ndara, A review on the use of cyclodextrins in foods, Food Hydrocolloids. 23 (2009) 1631–1640.

DOI: 10.1016/j.foodhyd.2009.01.001

Google Scholar

[5] S. Nagamoto, Cyclodextrin-expanding the development of their functions and applications, Chem. Economy & Engr Rev. 17 (1985) 28-34.

Google Scholar

[6] H. S. Kwak, C. S. Jung, J. S. Seok, & J. Ahn, Cholesterol Removal and Flavor Development in Cheddar Cheese . Received June 10, 2002; Accepted September 26, 2002.

Google Scholar

[7] B. Brajesh, K. Praveen, B. Anirban, C. L. Kaul, C. L. Banerjee, Cyclodextrins emerging applications. Chemistry Today, September (2003)

Google Scholar

[8] J-K. Choi, T. Girek, D-H. Shin, S-T. Lim, Structural and physical Characterization of octenylsuccinyl β-cyclodextrin, Carbohydrate Polymers. 49 (2002) 289-296.

DOI: 10.1016/s0144-8617(01)00336-8

Google Scholar

[9] C. A. Aziz, & M. S. Denise, Method for reduction of cholesterol in egg materials, US International Patent. (1996) 5,484,624.

Google Scholar

[10] R. Ficarra, P. Ficarra, D. M. R. Bella, D. Raneri, S. Tommasini, M. L. Calabro`, A. Villari, S. Coppolino, Study of the inclusion complex of atenolol with β-cyclodextrins, Journal of Pharmaceutical and Biomedical Analysis. 23 (2000) 231–236.

DOI: 10.1016/s0731-7085(00)00274-0

Google Scholar

[11] S. M., Mel'nikov, J. W. S. t. Hoorn, B. Bertrand, Can cholesterol absorption be reduced by phytosterols and phytostanols via a cocrystallization mechanism?, Chemistry and Physics of Lipids. 127 (2004) (1) 15-33.

DOI: 10.1016/j.chemphyslip.2003.08.007

Google Scholar

[12] P. Kanchana, & C. Sekar, Effect of fluoride on the crystallization and spectral properties of cholesterol, Indian Journal Of Pure & Applied Physics. 49 (2011) 539-544.

Google Scholar

[13] T. Higuchi & K. A. Connors, Phase-solubility techniques, Advance Analytical Chemistry Instruments. 4 (1965) 117–212.

Google Scholar

[14] R.O. Williams III, V. Mahaguna, M. Sriwongjanya, Characterization of an inclusion complex of cholesterol and hydroxypropyl-β-cyclodextrin. European Journal of Pharmaceutics and Biopharmaceutics, 46 (1998) 355-360.

DOI: 10.1016/s0939-6411(98)00033-2

Google Scholar

[15] L. Liu, & S. Zhu, A study on the supramolecular structure of inclusion complex of b-cyclodextrin with prazosin hydrochloride, Carbohydrate Polymers. 68 (2007) 472-476.

DOI: 10.1016/j.carbpol.2006.11.007

Google Scholar