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HomeJournal of Nano ResearchJournal of Nano Research Vol. 59Effect of Synthesis Conditions on...

Effect of Synthesis Conditions on Pseudocapacitance Properties of Nitrogen-Doped Porous Carbon Materials

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Abstract:

The electrochemical properties of the nitrogen-enriched carbons obtained by plant raw treatment as electrode material for supercapacitors were investigated by electrochemical impedance spectroscopy, cycling voltammetry and galvanostatic charge-discharge cycling in KOH aqueous electrolyte. The effect of activation agent (NaOH) concentration and carbonization temperature were analyzed. The separation of double layer and redox capacitance components was done. The dominating role of microporosity for capacitive properties was demonstrated. The capacitance of model capacitors based on carbons obtained at different modes was calculated from both from cycling voltammetry and galvanostatic charge-discharge data. The maximal values of specific capacitance of carbon materials carbonized at 600°C and 900°C are about 100 and 120 F/g, respectively.

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Journal of Nano Research Vol. 59

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Periodical:

Journal of Nano Research (Volume 59)

Pages:

112-125

DOI:

https://doi.org/10.4028/www.scientific.net/JNanoR.59.112

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Online since:

August 2019

Authors:

Volodymyra Boychuk, Volodymyr Kotsyubynsky*, Andrii Kachmar, Sergiy Budzulyak, Ivan Budzulyak, Bogdan Rachiy, Lyubov Yablon

Keywords:

Impedance Spectroscopy, Nitrogen-Doped Carbon, Pseudocapacitance, Raman Spectroscopy, Supercapacitor

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* - Corresponding Author

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