Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Articles
A New Accelerated Durability Test Protocol for Water Oxidation Electrocatalysts of Renewable Energy Powered Alkaline Water Electrolyzers
Ashraf ABDEL HALEEMKensaku NAGASAWAYoshiyuki KURODAYoshinori NISHIKIAwaludin ZAENALShigenori MITSUSHIMA
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JOURNAL OPEN ACCESS
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2021 Volume 89 Issue 2 Pages 186-191

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Abstract

For electrocatalysts of oxygen evolution reaction (OER), a new accelerated durability test (ADT) protocol is presented. The protocol is designed to closely mimic the fluctuations of renewable energies. The unit cycle of the current ADT protocol represents the “ON/OFF” operation mode. In the “ON” step, the electrolyzer operates under a DC current of 0.6 A cm−2. In the “OFF” step, the electrocatalyst is subjected to a constant potential that is clearly more cathodic than its OER onset potential (namely, 0.3, 0.5, and 0.7 V vs. RHE) for 10 or 60 s. The transition from the “ON” state to the “OFF” state occurs through a cathodic linear sweep voltammetry of a fast sweep rate to mimic the sudden changes in the renewable power. A NiCoOx/Ni-mesh electrode was used as a case study. The electrode showed remarkable durability under continuous operation (i = 0.6 A cm−2) for about 900 hours. However, it did suffer severe degradation after a certain number of ADT cycles, and the rate of degradation mainly depends on the potential value and the duration of the “OFF” step. Interestingly, the inclusion of the 10-sec open-circuit potential step after the “ON” step clearly mitigates the impact of energy fluctuations on the durability of OER electrocatalysts.

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© The Author(s) 2020. Published by ECSJ.

This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium provided the original work is properly cited. [DOI: 10.5796/electrochemistry.20-00156].
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