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Article

Deactivation of a Pd/Pt Bimetallic Oxidation Catalyst Used in a Biogas-Powered Euro VI Heavy-Duty Engine Installation

by
Johanna Englund
1,*,
Kunpeng Xie
2,
Sandra Dahlin
3,
Andreas Schaefer
1,
Dazheng Jing
2,
Soran Shwan
2,
Lennart Andersson
2,
Per-Anders Carlsson
1,
Lars J. Pettersson
3 and
Magnus Skoglundh
1
1
Competence Centre for Catalysis, Department of Chemistry and Chemical Engineering, Chalmers University of Technology, 41296 Gothenburg, Sweden
2
Volvo Group Trucks Technology, 41296 Gothenburg, Sweden
3
Department of Chemical Engineering, KTH Royal Institute of Technology, 00000 Stockholm, Sweden
*
Author to whom correspondence should be addressed.
Catalysts 2019, 9(12), 1014; https://0-doi-org.brum.beds.ac.uk/10.3390/catal9121014
Submission received: 9 October 2019 / Revised: 22 November 2019 / Accepted: 28 November 2019 / Published: 2 December 2019
(This article belongs to the Section Environmental Catalysis)
Browse Figures
Versions Notes

Abstract

:
The reduction of anthropogenic greenhouse gas emissions is crucial to avoid further warming of the planet. We investigated how effluent gases from a biogas powered Euro VI heavy-duty engine impact the performance of a bimetallic (palladium and platinum) oxidation catalyst. Using synthetic gas mixtures, the oxidation of NO, CO, and CH4 before and after exposure to biogas exhaust for 900 h was studied. The catalyst lost most of its activity for methane oxidation, and the activity loss was most severe for the inlet part of the aged catalyst. Here, a clear sintering of Pt and Pd was observed, and higher concentrations of catalyst poisons such as sulfur and phosphorus were detected. The sintering and poisoning resulted in less available active sites and hence lower activity for methane oxidation.

1. Introduction

To mitigate the negative impacts of emissions on health and the environment from the transportation sector, emission legislation is applied around the world. The legislation regulates the emission levels of nitrogen oxides (NOx), particulate matter (PM), carbon monoxide (CO), and hydrocarbons (HC). Regulations restricting the emissions of CO2 will be more common and are already in place in some parts of the world [1]. The emissions from a vehicle must not exceed certain levels over the lifetime of the vehicle or a certain distance of use, which for heavy-duty vehicles in Europe presently is seven years or 700,000 km, respectively [2]. There are several approaches toward the reduction of CO2 emissions from vehicles. One of these approaches is to increase the efficiency of the engine to reduce the amount of fuel that is used. However, a more efficient engine could lead to a reduction in exhaust temperature. This will put more pressure on the development of catalytic materials that have higher efficiency at lower temperatures, to be able to comply with regulations [3]. Another approach to reduce the emissions of fossil CO2 to the atmosphere is to increase the use of biofuels such as biogas. One possible disadvantage of using biofuels could be the presence of impurities in the fuel, which will impact the durability of the aftertreatment catalysts of the vehicle. The presence of impurities in biogas is dependent on the feedstock, as this type of fuel can be produced from several different feedstocks, causing different compositions of impurities in the final fuel. Some of the most potent catalyst poisons that could be present in the fuel and/or lubrication oil are sulfur, phosphorus, and siloxanes [4].
Bi-metallic Pd/Pt catalysts are today commonly used for oxidation of CO, HC, and NO in the aftertreatment system in vehicles [5,6]. The role of palladium in these catalysts is to be active for oxidation of methane; however, palladium based catalysts are sensitive to the presence of water vapor and tend to lose activity over time due to hydrothermal sintering [7,8,9,10]. As water is always present in the combustion exhaust, palladium based catalysts are often modified by the addition of platinum, which stabilizes the active metal particles and makes them less prone to sintering [11]. Besides sintering [12], oxidation catalysts may deactivate by other mechanisms [13,14,15], one of the most studied of which is SO2 poisoning [16,17,18,19]. The bi-metallic catalysts can be deactivated by poisoning and sintering of precious metal particles similar to mono-metallic catalysts. However, the bi-metallic catalysts may in addition suffer from segregation of the metals as shown by Gremminger et al. The Pd/Pt bi-metallic catalyst is dynamic and presents surface species that are dependent on the reaction condition [20], and when exposed to water, these Pd/Pt species could segregate [21]. This segregation of platinum and palladium into mono-metallic particles impacts the stability and activity of the catalyst. Many studies are focused on a single poison at the lab scale [12,16,17,18,21,22], while others compare the impact of lab aging and vehicle aging [22,23,24].
In the present study, the impact of biogas exhaust on the oxidation catalyst performance is investigated. The exhaust exposure is conducted for 900 h in an engine bench setup with a full Euro VI emission control system. In that way, an understanding of how the use of biogas impacts the oxidation catalyst in a real-life exhaust environment can be achieved.

2. Results and Discussion

The catalyst samples used are named according to Table 1.
Figure 1a–c shows the conversion of CH4, NO, and CO versus temperature using a feed consisting of the mentioned gases, water, oxygen, and argon as balance. Results are shown for the fresh Pd/Pt oxidation catalyst (DOC ref) and for an inlet (DOC in) and an outlet (DOC out) sample of the catalyst after 900 h aging with biogas exhaust in the engine bench. The performance of the samples was measured during heating and cooling ramps between 100 and 450 °C at a rate of 5 °C/min. The conversion performance of the catalysts to oxidize each of these compounds was also measured separately. The results for these experiments are shown in Figure 1d–f. From the results of the heating ramp experiments presented in Figure 1a,d, it is clear that the exposure to biogas exhaust results in a considerable decrease in the catalyst’s ability to oxidize CH4, in particular for the inlet part of the engine aged catalyst. It can also be observed that the complex gas mixture results in a higher conversion of CH4 than what is obtained without CO and NO in the feed, as shown in Figure 1d and Table 2. The presence of NO during methane oxidation has been shown to be beneficial in studies by Sadokhina et al. [25]. These authors suggested that the improved activity originates from the reaction between NO and hydroxyl groups on the surface of the active phase, leaving more active sites available for methane oxidation.
Downstream of the oxidation catalyst and the particulate filter in the emission control system is the selective catalytic reduction (SCR) catalyst, which reduces NOx into nitrogen and water. The NOx reduction can take place by several different routes depending on the NO/NOx ratio [26]. The route that is desired is the fast-SCR reaction, which is followed when the NO/NOx ratio is around 0.5. In Figure 1b,e, the conversion of NO to NO2 over the oxidation catalyst is shown. At lower temperatures, the samples exposed to biogas exhaust show lower activity for oxidation of NO, when compared to the reference sample, in both gas mixtures, and the outlet part of the engine aged oxidation catalyst appears to have lost slightly more of its activity. However, at temperatures above 300 °C, the inlet sample of the aged oxidation catalyst shows a higher or similar conversion of NO in both gas compositions. It has been shown by Mulla et al. [27] that larger Pt particles are more active for oxidation of NO compared to smaller ones, and as seen from the TEM images in Figure 2, the noble metal particle size has increased after exposure of the oxidation catalyst to biogas exhaust, in particular for the inlet sample, due to sintering. Furthermore, a separation of the conversion maximum of NO into two peaks is visible for the samples exposed to biogas. This double peak could be caused by the segregation of Pd/Pt into mono-metallic sites. Platinum is more active for NO oxidation when compared to palladium, and as mentioned, large Pt particles are especially active for NO oxidation [28]. Hence, the double peak appears only for the engine bench aged samples where large mono-metallic Pt particles likely have formed and not for the fresh sample of the oxidation catalyst.
After exposure to biogas exhausts, the temperature where 50% conversion (T50) of CO is reached is shifted 25 °C towards higher temperatures in the complex gas feed and 50 °C in the feed with only CO besides oxygen, water, and argon, see Table 2. For CO, the decrease in activity of the oxidation catalyst after exposure to biogas exhaust is evident from Figure 1c,f; however, the decrease in activity is not as severe as for CH4. The impact of the other components in the complex feed on the conversion of CO is clear when comparing Figure 1c and Figure 1f. In the presence of NO and methane, the activity for CO oxidation is significantly lower for both the fresh and the engine aged catalysts compared to the corresponding feed without CH4 and NO (see Table 2).
The content of sulfur (S), phosphorus (P), and calcium (Ca) in the fresh and aged oxidation catalysts is shown in Table 3. The table also shows the composition of the catalyst in terms of Pt and Pd content; note that the reference sample has a slightly lower content of noble metals. This could be due to the fact that the fresh and engine aged samples come from different batches. The catalyst cores used in the engine bench setup are cut from longer cores produced by the catalyst manufacturer. There is a gradient in coating over the length of the catalyst, which could cause a difference in catalyst loading between the samples. It can be seen that S, P, and Ca are found in higher concentrations on the inlet sample of the engine bench aged oxidation catalyst compared to the corresponding outlet sample. It is also seen that the concentrations of S and P are substantially higher than the concentration of Ca. This is expected since the former two compounds are present in higher concentrations in both the fuel and the lubrication oil [29], while Ca is a component only present in the lubrication oil [23].
In the TEM images, the Pt/Pd, Pt, and Pd particles are shown as bright dots, as can be seen in Figure 2. It is clear that the particle size has increased for the samples exposed to biogas exhaust (Figure 2b,c,e,f). The average noble metal particle size was calculated on the basis of 100 particles, and the result is summarized in Table 4, where the particle size distribution is also included. The size of the active metal particles in the oxidation catalyst increased after exposure to biogas exhaust in the engine bench, likely due to thermal effects [23]. On the other hand, the temperature measured in the oxidation catalyst during aging did not exceed 550 °C, which means that sintering should not be severe. However, the presence of sulfur and phosphorus in the engine exhaust has been shown to promote sintering of Pt into larger particles [30,31]. The combination of long term exposure in an oxidizing environment at temperatures up to 550 °C, in combination with the presence of sulfur and phosphorus in the exhaust, is probably the cause of the observed sintering of Pt.
From the X-ray diffractograms shown in Figure 3, it is evident that the peak around 40 degrees (2Θ) is shifted towards higher angles for the aged samples, in particular for the inlet sample of the engine bench aged oxidation catalyst. This indicates that the bimetallic catalyst has more mono-metallic sites, and in combination with the increased intensity of that peak, it is clear that there are larger mono-metallic particles present after aging of the catalyst [32,33,34,35]. The increased intensity is also seen for the Pd peak around 46.5 degrees, which is in agreement with the TEM analysis and activity tests, also showing that the particle size is increased and that more mono-metallic particles are present after exposure to biogas exhaust.
The poisoning by S and P indicated by the presence of these elements (see Table 3) and the increased Pd/Pt particle size (Figure 2) will cause blocking and loss of active sites, respectively. The blocking and loss of active sites can clearly be seen from the CO chemisorption measurements presented in Table 4. The amount of CO that is chemisorbed on equimolar amounts of noble metal strongly decreases for the samples that have been exposed to biogas exhaust for 900 h in the engine bench compared to the reference sample of the oxidation catalyst.
Table 3 indicates that sulfur is uniformly distributed over the length of the engine bench aged oxidation catalyst, while phosphorus is found in higher concentrations in the inlet of the catalyst, in agreement with previous studies [13,36,37]. This could also be seen from the SEM-EDX analysis (Figure 4) where phosphorus is mapped in yellow. The concentration of P is clearly higher on the surface of the washcoat for the inlet sample of the engine bench aged oxidation catalyst, while S is more evenly distributed over the washcoat, as well as the length of the catalyst [38]. The increased concentration of P on the inlet sample of the engine bench aged oxidation catalyst, when compared to the corresponding outlet sample, results in fewer available active sites. This, together with the loss of active sites due to Pd/Pt sintering, could explain the measured difference in activity for methane oxidation for the fresh and aged samples; see Figure 1a,d.
From the XPS analysis, it is clear that several elements are present on the surface of the samples. The survey spectra with assigned peaks for Pd, Pt, Al, Si, C, and O are included in the Supporting Information (see Figure A1 and Figure A2 ) for clarification. From the XPS spectra shown in Figure 5 (left column), we found that phosphorus is present in the inlet sample of the engine bench aged oxidation catalyst in two different forms, as phosphate (135 eV) and oxidized phosphorus (likely at 138 eV) [39]. P4O10, also known as phosphate glass, covers the surface of the sample in a non-selective way, while the phosphates could form bonds with the alumina support [40,41]. For the outlet sample of the engine bench aged oxidation catalyst, mainly phosphate is found, and this is most likely due to P4O10 sticking to the first surface it comes in contact with, which is the inlet of the oxidation catalyst. From the XPS analysis, we can also see that sulfur is present in the form of sulfate on both engine bench aged samples. Sulfates primarily form PdSO4 at ambient pressure, and no or minor formation of PtSO4 is expected [42,43]. In agreement with the XRF analysis, neither sulfur nor phosphorus is found on the reference sample

3. Materials and Methods

The aging of the catalysts was performed in an engine bench consisting of a Volvo G13C 460 hp engine and a Euro VI emission control system, and the setup is schematically shown in Figure 6. The engine was a dual-fuel type engine, which was powered with 90% biogas and 10% diesel for 900 h, during which the gas flow was altered to simulate mixed driving. The temperature in the engine bench was kept between 170 and 550 °C throughout the duration of the aging. After exposure to biogas exhausts for 900 h, the emission control system was dismantled, and the parts were characterized and tested separately.

3.1. Catalyst Material

The oxidation catalyst used in this study was a Pd/Pt based catalyst supported on alumina (Al2O3) and washcoated onto a cordierite substrate. The catalyst samples were provided by a catalyst manufacturer, and no further specification of the sample preparation procedure is available. Full size bricks were used in the engine bench while sample cores with a diameter 11 mm and a length 19 mm were drilled out and tested in the synthetic gas bench reactor. The noble metal loading of the catalyst was 100 g/ft3, and the Pt:Pd ratio was 1:2 by weight. Samples were taken from the inlet and the outlet of the oxidation catalyst to observe any axial differences downstream of the catalyst. The engine bench aged samples of the oxidation catalyst were compared with a fresh sample. The cell density of the oxidation catalyst was 400 cpsi.

3.2. Activity Testing

The catalyst activity during CO, CH4, and NO oxidation was evaluated in a synthetic gas bench reactor. The activity of the catalyst (DOC) to oxidize each gaseous compound was evaluated separately, as well as in a complex mixture. The experimental conditions are shown in Table 5. The synthetic gas bench reactor, described in detail elsewhere [44], consisted of a horizontal quartz tube heated by a resistive heating coil. The gas flow was controlled by Hi-Tech Bronkhorst mass flow controllers. The water was fed by a Bronkhorst CEM system, and the effluent gases were analyzed by an MKS 2030 HS Fourier transform infrared spectrometer (FTIR). Thermocouples were placed in a blank monolith substrate upstream of the oxidation catalyst for temperature control and in the center of the oxidation catalyst for temperature monitoring.

3.3. Characterization

3.3.1. SEM-EDX

The radial distribution and position of elements were mapped using a Hitachi SU-500 scanning electron microscope (SEM, AB Volvo, Gothenburg, Sweden) equipped with an energy-dispersive X-ray (EDX, AB Volvo, Gothenburg, Sweden) analysis system, Oxford Instruments SDD 80 mm2. Full cores were cut from the fresh and engine bench aged samples, and 10 mm thick slices were cut from the cores, then the untreated uncut surface was analyzed.

3.3.2. Elemental Analysis Using XRF

A PANalytical Epsilon 3XL analyzer ( Scania CV, Södertälje, Sweden and Chalmers University of Technology, Gothenburg, Sweden) was used to perform X-ray fluorescence (XRF) analysis to determine semi-quantitatively the elemental composition of the fresh and engine bench aged catalyst samples. For the analysis, around 2 g of each of the samples was needed, and the washcoat and cordierite substrate were analyzed together. The samples were mixed with a binder using a ball mill (300 rpm, 10 min) and then pressed into flat briquettes (150 kN, 3 min). This method does not quantify the amount of catalyst poisons in the samples exactly, but for comparison of poison content between similar samples, the method is satisfying. The measurement was performed tree times to receive an error margin.

3.3.3. TEM

Transmission electron microscopy (TEM) was performed using an FEI Titan 80–300 instrument operating at an accelerating voltage of 300 kV (Chalmers University of Technology, Gothenburg, Sweden). Images were acquired in the scanning TEM (STEM) mode using a high angle annular dark field (HAADF) detector. The average noble metal particle size and the particle size distribution for each catalyst sample were determined from these images. A small amount of washcoat was scraped off from the monolith sample and transferred to a copper grid. Images were recorded at several different magnifications for each sample.

3.3.4. XRD

XRD (X-ray diffraction) was used to determine if segregation of Pd and Pt occurred during engine bench aging. The X-ray diffractometer used was a Bruker axs D8 ADVANCE instrument (Chalmers University of Technology, Gothenburg, Sweden) with a Cu K α radiation equivalent to 0.15418 nm. The washcoat was scraped off, and the powder sample was transferred to a sample holder with a silicon wafer as the base. Diffraction data were collected for 2 θ = 30–90°.

3.3.5. XPS

The presence and chemical state of the elements on the surface of the catalyst samples were identified by X-ray photoelectron spectroscopy (XPS) using a VersaProbe III Scanning XPS Microprobe ( Chalmers University of Technology, Gothenburg, Sweden) with an Al anode providing monochromated K α radiation (1486.6 eV). For charge compensation, both an ion gun (Ar+) and electron neutralizer (e−) were used. The sample was prepared by cutting out six channels from the monolith core and attaching them by using double sided carbon tape. The analyzed area was 500 × 500 μm2, and the information depth was around 5 nm. The binding energy scale was calibrated to the position of the Si 2p signal of SiO2 at 103.3 eV [45], because the nature of the varying amount of carbon present on the different samples could not be determined with certainty, and hence, calibration to the carbon signal was unreliable. We estimated an accuracy of ± 0.5 eV for the binding energy. The spectra were normalized to the background at the low binding energy end. The P 2p and S 2p spectra in Figure 5 were deconvoluted using a Voigt profile with a spin-orbit split of Δ = 0.85 eV for P 2p and Δ = 1.18 eV for S 2p, respectively [45]. A linear background was subtracted prior to deconvolution.

3.3.6. CO Chemisorption

To quantify the active sites on the catalyst, CO chemisorption was performed using an ASAP2020 instrument from Micromeritics (Chalmers University of Technology, Gothenburg, Sweden). The samples were prepared by cutting out 3 × 3 channels from each catalyst sample. The sample was then confined between folded quartz wool and oxidized at 350 °C for 1 h followed by evacuation for 15 min and reduction by hydrogen at 350 °C for 1 h. The pretreatment was finalized by evacuation at 350 and 35 °C for 10 min each. The CO chemisorption measurement was performed at 35 °C by gradually increasing the CO dosage from 100 to 600 mm Hg.

3.4. Biogas

Biogas refers to gases produced by anaerobic fermentation or digestion of organic matter like sewage waste [46]. The biogas used for aging in this study follows European standards, which means that the concentrations of impurities like sulfur are limited. The total sulfur content in biogas, excluding odorant, should be below 20 mg/m3 [47].

4. Conclusions

The exhaust from a dual-fuel heavy-duty engine powered by biogas and equipped with a Euro VI emission control system was shown to have a significant impact on the CH4 oxidation activity of the Pd/Pt bimetallic oxidation catalyst. We could also observe that the activity for CO oxidation decreased while the activity for NO oxidation increased for the inlet of the oxidation catalyst after 900 h of exposure to biogas exhausts. The loss of activity for CH4 and CO oxidation was likely caused by loss of active sites by sintering and poisoning by sulfur and phosphorus. The explanation for the increased NO oxidation at higher temperatures was that larger Pt particles had higher activity for oxidation of NO to NO2. Evidence of sintering was seen in the results from TEM and XRD analysis, and indications of sintering/poisoning could be seen in the decrease in CO uptake during CO chemisorption for the aged catalyst. The presence of catalyst poisons, i.e., S and P, was confirmed by XRF, XPS, and SEM-EDX. The distribution of sulfur was uniform throughout the washcoat and the length of the aged oxidation catalyst, while higher concentrations of phosphorus were seen on the surface of the washcoat and in the inlet of the catalyst. Sulfur was present in the form of sulfates, which mainly react with Pd sites. Phosphorus, however, was found in two different states where the P4O10 state was only found in the inlet of the aged catalyst, while phosphates were present both in the inlet and outlet of the aged catalyst. Both phosphorus states covered the surface, and the phosphate could also react with the alumina support. To ensure a good transition from the use of fossil fuels to more bio based fuels, optimization of the oxidation catalyst is needed, in particular for the oxidation of methane.

Author Contributions

Conceptualization, L.J.P. and M.S.; Data curation, J.E., D.J., A.S. and S.D.; Formal analysis, J.E., D.J., S.D., A.S., L.J.P. and M.S.; Funding acquisition, L.J.P. and M.S.; Investigation, J.E. and K.X.; Methodology, J.E., K.X., S.S., L.A., L.J.P. and M.S.; Project administration, J.E.; Resources, K.X., D.J., S.D., A.S., S.S. and L.A.; Supervision, K.X., S.S., L.A., P.-A.C., L.J.P. and M.S.; Visualization, J.E.; Writing—original draft, J.E.

Funding

This work was financially supported by the Swedish Energy Agency through the FFI program (No: 38364-1) and the Competence Centre for Catalysis, which is financially supported by Chalmers University of Technology, the Swedish Energy Agency, and the member companies AB Volvo, ECAPS AB, Johnson Matthey AB, Preem AB, Scania CV AB, Umicore Denmark ApS, and Volvo Car Corporation AB.

Conflicts of Interest

The authors declare no conflict of interest.

Appendix A

Appendix A.1. XRD

Catalysts 09 01014 g0a1 550
Figure A1. Full XRD diffractograms for the fresh (DOC ref) and the inlet of the engine bench aged (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
Figure A1. Full XRD diffractograms for the fresh (DOC ref) and the inlet of the engine bench aged (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
Catalysts 09 01014 g0a1

Appendix A.2. XPS

Catalysts 09 01014 g0a2a 550Catalysts 09 01014 g0a2b 550
Figure A2. Full XPS survey spectra for the fresh oxidation catalyst (DOC ref) and the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
Figure A2. Full XPS survey spectra for the fresh oxidation catalyst (DOC ref) and the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
Catalysts 09 01014 g0a2aCatalysts 09 01014 g0a2b

References

  1. Regulation (EU) 2019/631. Off. J. Eur. Union 2019. Available online: https://eur-lex.europa.eu/eli/reg/2019/631/oj (accessed on 9 October 2019).
  2. Regualtions No 595/2009. Off. J. Eur. Union 2009. Available online: https://eur-lex.europa.eu/eli/reg/2009/595/oj (accessed on 9 October 2019).
  3. Binder, A.J.; Toops, T.J.; Unocic, R.R.; Parks, J.E., II; Dai, S. Low-Temperature CO Oxidation over a Ternary Oxide Catalyst with High Resistance to Hydrocarbon Inhibition. Angew. Chem. Int. Ed. 2015, 54, 13263–13267. [Google Scholar] [CrossRef] [PubMed]
  4. Chiodo, V.; Maisano, S.; Zafarana, G.; Urbani, F. Effect of pollutants on biogas steam reforming. Int. J. Hydrog. Energy 2017, 42, 1622–1628. [Google Scholar] [CrossRef]
  5. Martin, N.M.; Nilsson, J.; Skoglundh, M.; Adams, E.C.; Wang, X.; Smedler, G.; Raj, A.; Thompsett, D.; Agostini, G.; Carlson, S.; et al. Study of methane oxidation over alumina supported Pd–Pt catalysts using operando DRIFTS/MS and in situ XAS techniques. Catal. Struct. React. 2017, 3, 24–32. [Google Scholar] [CrossRef]
  6. Martin, N.M.; Skoglundh, M.; Smedler, G.; Raj, A.; Thompsett, D.; Velin, P.; Martinez-Casado, F.J.; Matej, Z.; Balmes, O.; Carlsson, P.A. CO Oxidation and Site Speciation for Alloyed Palladium–Platinum Model Catalysts Studied by in Situ FTIR Spectroscopy. J. Phys. Chem. C 2017, 121, 26321–26329. [Google Scholar] [CrossRef]
  7. Lapisardi, G.; Urfels, L.; Gélin, P.; Primet, M.; Kaddouri, A.; Garbowski, E.; Toppi, S.; Tena, E. Superior catalytic behaviour of Pt-doped Pd catalysts in the complete oxidation of methane at low temperature. Catal. Today 2006, 117, 564–568. [Google Scholar] [CrossRef]
  8. Ersson, A.; Kušar, H.; Carroni, R.; Griffin, T.; Järås, S. Catalytic combustion of methane over bimetallic catalysts a comparison between a novel annular reactor and a high-pressure reactor. Catal. Today 2003, 83, 265–277. [Google Scholar] [CrossRef]
  9. Kinnunen, N.M.; Hirvi, J.T.; Suvanto, M.; Pakkanen, T.A. Methane combustion activity of Pd–PdOx–Pt/Al2O3 catalyst: The role of platinum promoter. J. Mol. Catal. A Chem. 2012, 356, 20–28. [Google Scholar] [CrossRef]
  10. Morlang, A.; Neuhausen, U.; Klementiev, K.; Schütze, F.W.; Miehe, G.; Fuess, H.; Lox, E. Bimetallic Pt/Pd diesel oxidation catalysts: Structural characterisation and catalytic behaviour. Appl. Catal. B Environ. 2005, 60, 191–199. [Google Scholar] [CrossRef]
  11. Honkanen, M.; Kärkkäinen, M.; Viitanen, V.; Jiang, H.; Kallinen, K.; Huuhtanen, M.; Vippola, M.; Lahtinen, J.; Keiski, R.; Lepistö, T. Structural Characteristics of Natural-Gas-Vehicle-Aged Oxidation Catalyst. Top. Catal. 2013, 56, 576–585. [Google Scholar] [CrossRef]
  12. González-Velasco, J.R.; Botas, J.A.; Ferret, R.; González-Marcos, M.P.; Marc, J.L.; Gutiérrez-Ortiz, M.A. Thermal aging of Pd/Pt/Rh automotive catalysts under a cycled oxidizing–reducing environment. Catal. Today 2000, 59, 395–402. [Google Scholar] [CrossRef]
  13. Neyestanaki, A.K.; Klingstedt, F.; Salmi, T.; Murzin, D.Y. Deactivation of postcombustion catalysts, a review. Fuel 2004, 83, 395–408. [Google Scholar] [CrossRef]
  14. Forzatti, P.; Lietti, L. Catalyst deactivation. Catal. Today 1999, 52, 165–181. [Google Scholar] [CrossRef]
  15. Kim, J.; Kim, Y.; Wiebenga, M.H.; Oh, S.H.; Kim, D.H. Oxidation of C3H8, iso-C5H12 and C3H6 under near-stoichiometric and fuel-lean conditions over aged Pt–Pd/Al2O3 catalysts with different Pt:Pd ratios. Appl. Catal. B Environ. 2019, 251, 283–294. [Google Scholar] [CrossRef]
  16. Corro, G.; Cano, C.; Fierro, J. A study of Pt-Pd/γ-Al2O3 catalysts for methane oxidation resistant to deactivation by sulfur poisoning. J. Mol. Catal. A Chem. 2010, 315, 35–42. [Google Scholar] [CrossRef]
  17. Mowery, D.L.; McCormick, R.L. Deactivation of alumina supported and unsupported PdO methane oxidation catalyst: The effect of water on sulfate poisoning. Appl. Catal. B Environ. 2001, 34, 287–297. [Google Scholar] [CrossRef]
  18. Ordóñez, S.; Hurtado, P.; Sastre, H.; Díez, F. Methane catalytic combustion over Pd/Al2O3 in presence of sulphur dioxide: Development of a deactivation model. Appl. Catal. A Gen. 2004, 259, 41–48. [Google Scholar] [CrossRef]
  19. Colussi, S.; Arosio, F.; Montanari, T.; Busca, G.; Groppi, G.; Trovarelli, A. Study of sulfur poisoning on Pd/Al2O3 and Pd/CeO2/Al2O3 methane combustion catalysts. Catal. Today 2010, 155, 59–65. [Google Scholar] [CrossRef]
  20. Martin, N.M.; Nilsson, J.; Skoglundh, M.; Adams, E.C.; Wang, X.; Velin, P.; Smedler, G.; Raj, A.; Thompsett, D.; Brongersma, H.H.; et al. Characterization of Surface Structure and Oxidation/Reduction Behavior of Pd–Pt/Al2O3 Model Catalysts. J. Phys. Chem. C 2016, 120, 28009–28020. [Google Scholar] [CrossRef]
  21. Gremminger, A.T.; de Carvalho, H.W.P.; Popescu, R.; Grunwaldt, J.D.; Deutschmann, O. Influence of gas composition on activity and durability of bimetallic Pd-Pt/Al2O3 catalysts for total oxidation of methane. Catal. Today 2015, 258, 470–480. [Google Scholar] [CrossRef]
  22. Dahlin, S.; Lantto, C.; Englund, J.; Westerberg, B.; Regali, F.; Skoglundh, M.; Pettersson, L.J. Chemical aging of Cu-SSZ-13 SCR catalysts for heavy-duty vehicles—Influence of sulfur dioxide. Catal. Today 2019, 320, 72–83. [Google Scholar] [CrossRef]
  23. Andersson, J.; Antonsson, M.; Eurenius, L.; Olsson, E.; Skoglundh, M. Deactivation of diesel oxidation catalysts: Vehicle- and synthetic aging correlations. Appl. Catal. B Environ. 2007, 72, 71–81. [Google Scholar] [CrossRef]
  24. Wiebenga, M.H.; Kim, C.H.; Schmieg, S.J.; Oh, S.H.; Brown, D.B.; Kim, D.H.; Lee, J.H.; Peden, C.H. Deactivation mechanisms of Pt/Pd-based diesel oxidation catalysts. Catal. Today 2012, 184, 197–204. [Google Scholar] [CrossRef]
  25. Sadokhina, N.; Smedler, G.; Nylén, U.; Olofsson, M.; Olsson, L. The influence of gas composition on Pd-based catalyst activity in methane oxidation—Inhibition and promotion by NO. Appl. Catal. B Environ. 2017, 200, 351–360. [Google Scholar] [CrossRef]
  26. Devadas, M.; Kröcher, O.; Elsener, M.; Wokaun, A.; Söger, N.; Pfeifer, M.; Demel, Y.; Mussmann, L. Influence of NO2 on the selective catalytic reduction of NO with ammonia over Fe-ZSM5. Appl. Catal. B Environ. 2006, 67, 187–196. [Google Scholar] [CrossRef]
  27. Mulla, S.; Chen, N.; Cumaranatunge, L.; Blau, G.; Zemlyanov, D.; Delgass, W.; Epling, W.; Ribeiro, F. Reaction of NO and O2 to NO2 on Pt: Kinetics and catalyst deactivation. J. Catal. 2006, 241, 389–399. [Google Scholar] [CrossRef]
  28. Dubbe, H.; Bühner, F.; Eigenberger, G.; Nieken, U. Hysteresis Phenomena on Platinum and Palladium-based Diesel Oxidation Catalysts (DOCs). Emiss. Control. Sci. Technol. 2016, 2, 137–144. [Google Scholar] [CrossRef]
  29. Jääskeläinen, H. Impact of Engine Oil on Emissions and Fuel Economy; Dieselnet: 2015. Available online: https://www.dieselnet.com/tech/lube_emissions.php (accessed on 9 October 2019).
  30. Fridell, E.; Amberntsson, A.; Olsson, L.; Grant, A.W.; Skoglundh, M. Platinum oxidation and sulphur deactivation in NOxstorage catalysts. Top. Catal. 2004, 30, 143–146. [Google Scholar] [CrossRef]
  31. Winkler, A.; Ferri, D.; Aguirre, M. The influence of chemical and thermal aging on the catalytic activity of a monolithic diesel oxidation catalyst. Appl. Catal. B Environ. 2009, 93, 177–184. [Google Scholar] [CrossRef]
  32. Martin-Martinez, M.; Gómez-Sainero, L.; Bedia, J.; Arevalo-Bastante, A.; Rodriguez, J. Enhanced activity of carbon-supported Pd–Pt catalysts in the hydrodechlorination of dichloromethane. Appl. Catal. B Environ. 2016, 184, 55–63. [Google Scholar] [CrossRef]
  33. Persson, K.; Ersson, A.; Colussi, S.; Trovarelli, A.; Järås, S. Catalytic combustion of methane over bimetallic Pd–Pt catalysts: The influence of support materials. Appl. Catal. B Environ. 2006, 66, 175–185. [Google Scholar] [CrossRef]
  34. Rodríguez-Proenza, C.; Palomares-Báez, J.; Chávez-Rojo, M.; García-Ruiz, A.; Azanza Ricardo, C.; Santoveña-Uribe, A.; Luna-Barcenas, G.; Rodríguez-López, J.; Esparza, R. materials Atomic Surface Segregation and Structural Characterization of PdPt Bimetallic Nanoparticles. Materials 2018, 11, 1882. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  35. Esparza, R.; Santoveña, A.; Ruíz-Baltazar, A.; Angeles-Pascual, A.; Bahena, D.; Maya-Cornejo, J.; Ledesma-García, J.; Perez-Campos, R. Study of PtPd Bimetallic Nanoparticles for Fuel Cell Applications. Mater. Res. 2017. [Google Scholar] [CrossRef] [Green Version]
  36. Corro, G. Sulfur impact on diesel emission control—A review. React. Kinet. Catal. Lett. 2002, 75, 89–106. [Google Scholar] [CrossRef]
  37. Haaß, F.; Fuess, H. Structural Characterization of Automotive Catalysts. Adv. Eng. Mater. 2005, 7, 899–913. [Google Scholar] [CrossRef]
  38. Cabello Galisteo, F.; Larese, C.; Mariscal, R.; Granados, M.; Fierro, J.; Fernández Ruiz, R.; Furió, M. Deactivation on Vehicle-Aged Diesel Oxidation Catalysts. Top. Catal. 2004, 30-31, 451–456. [Google Scholar] [CrossRef]
  39. Sherwood, P.M.A. Introduction to Studies of Phosphorus-Oxygen Compounds by XPS. Surf. Sci. Spectra 2002, 9, 62–66. [Google Scholar] [CrossRef]
  40. Kärkkäinen, M.; Kolli, T.; Honkanen, M.; Heikkinen, O.; Väliheikki, A.; Huuhtanen, M.; Kallinen, K.; Lahtinen, J.; Vippola, M.; Keiski, R.L. The Influence of Phosphorus Exposure on a Natural-Gas-Oxidation Catalyst. Top. Catal. 2016, 59, 1044–1048. [Google Scholar] [CrossRef]
  41. Eaton, S.J.; Nguyen, K.; Bunting, B.G. Deactivation of Diesel Oxidation Catalysts by Oil-Derived Phosphorus. Powertrain & Fluid Systems Conference and Exhibition. SAE Int. 2006. [Google Scholar] [CrossRef]
  42. Sharma, H.N.; Sharma, V.; Mhadeshwar, A.B.; Ramprasad, R. Why Pt Survives but Pd Suffers From SOx Poisoning? J. Phys. Chem. Lett. 2015, 6, 1140–1148. [Google Scholar] [CrossRef]
  43. Wilburn, M.S.; Epling, W.S. SO2 adsorption and desorption characteristics of bimetallic Pd-Pt catalysts: Pd:Pt ratio dependency. Catal. Today 2019, 320, 11–19. [Google Scholar] [CrossRef]
  44. Kannisto, H.; Ingelsten, H.H.; Skoglundh, M. Ag–Al2O3 catalysts for lean NOx reduction—Influence of preparation method and reductant. J. Mol. Catal. A Chem. 2009, 302, 86–96. [Google Scholar] [CrossRef]
  45. Moulder, J.F.; Stickle, W.F.; E.’Sobol, P.; Bomben, K.D. Handbook of X-ray Photoelectron Spectroscopy; Perkin-Elmer Corporation: Eden Prairie, MN, USA, 1992. [Google Scholar]
  46. Granestrand, J.; Dahlin, S.; Immele, O.; Schmalhorst, L.; Lantto, C.; Nilsson, M.; París, R.S.; Regali, F.; Pettersson, L.J. Catalytic aftertreatment systems for trucks fueled by biofuels—Aspects on the impact of fuel quality on catalyst deactivation. RSC Catal. 2018, 30, 64–145. [Google Scholar] [CrossRef]
  47. CEN-CENELEC. EN 16726:2015. 2015. Available online: https://infostore.saiglobal.com/preview/98703699482.pdf?sku=879417_saig_nsai_nsai_2089598 (accessed on 9 October 2019).
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Figure 1. Conversion during heating of (a,d) CH4, (b,e), NO and (c,f) CO over the fresh oxidation catalyst (DOC ref) and the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst. Top row (a–c), in a feed consisting of 1000 ppm CH4, 1000 ppm NO, 1000 ppm CO, 8% H2O, 5% O2, and argon as balance. Bottom row (d–f), in a feed consisting of 1000 ppm CH4 or 1000 ppm NO or 1000 ppm CO with 8% H2O, 5% O2, and argon as balance.
Figure 1. Conversion during heating of (a,d) CH4, (b,e), NO and (c,f) CO over the fresh oxidation catalyst (DOC ref) and the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst. Top row (a–c), in a feed consisting of 1000 ppm CH4, 1000 ppm NO, 1000 ppm CO, 8% H2O, 5% O2, and argon as balance. Bottom row (d–f), in a feed consisting of 1000 ppm CH4 or 1000 ppm NO or 1000 ppm CO with 8% H2O, 5% O2, and argon as balance.
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Figure 2. TEM images of (a,d) the fresh oxidation catalyst (DOC ref) and (b,e) the inlet (DOC in) and (c,f) outlet (DOC out) of the engine bench aged oxidation catalyst, at two magnifications, (a–c) and (d–f), respectively.
Figure 2. TEM images of (a,d) the fresh oxidation catalyst (DOC ref) and (b,e) the inlet (DOC in) and (c,f) outlet (DOC out) of the engine bench aged oxidation catalyst, at two magnifications, (a–c) and (d–f), respectively.
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Figure 3. X-ray diffractograms for the fresh oxidation catalyst (DOC ref) and for the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst. The diffraction patterns have been shifted in intensity for clarification, and full patterns between 30 and 90 degrees (2Θ) can be found in the Supporting Information. Diffraction peaks indicated by * show Pd.
Figure 3. X-ray diffractograms for the fresh oxidation catalyst (DOC ref) and for the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst. The diffraction patterns have been shifted in intensity for clarification, and full patterns between 30 and 90 degrees (2Θ) can be found in the Supporting Information. Diffraction peaks indicated by * show Pd.
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Figure 4. SEM images and EDX maps of Ca, P, S, Pt, and Pd for the fresh oxidation catalyst (DOC ref) and for the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
Figure 4. SEM images and EDX maps of Ca, P, S, Pt, and Pd for the fresh oxidation catalyst (DOC ref) and for the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
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Figure 5. Phosphorus and sulfur 2p core level spectra of the fresh oxidation catalyst (DOC ref) and of the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
Figure 5. Phosphorus and sulfur 2p core level spectra of the fresh oxidation catalyst (DOC ref) and of the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
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Figure 6. Emission control system setup with the oxidation catalyst (DOC), particulate filter (DPF), selective catalytic reduction (SCR) catalysts (SCR 1-3), and ammonia slip catalyst (ASC).
Figure 6. Emission control system setup with the oxidation catalyst (DOC), particulate filter (DPF), selective catalytic reduction (SCR) catalysts (SCR 1-3), and ammonia slip catalyst (ASC).
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Table
Table 1. Description of the catalyst samples.
Table 1. Description of the catalyst samples.
Sample NameDescription
DOCrefFresh sample of the oxidation catalyst
DOC inInlet sample of the engine bench aged oxidation catalyst
DOC outOutlet sample of the engine bench aged oxidation catalyst
Table
Table 2. Conversion of methane at 450 °C for 50% conversion of CO (T50) in a feed with and without NO and CO over the fresh oxidation catalyst (DOC ref) and the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
Table 2. Conversion of methane at 450 °C for 50% conversion of CO (T50) in a feed with and without NO and CO over the fresh oxidation catalyst (DOC ref) and the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst.
SampleConversion of CH4 in the Presence of NO and CO (%)Conversion of CH4 in Absence of NO and CO (%)T50 for CO in the Presence of NO and CO (°C)T50 for CO in the Absence of NO and CO (°C)
DOC ref8772166108
DOC in158192159
DOC out2615199161
Table
Table 3. Content of Pd, Pt, S, P, and Ca in the fresh oxidation catalyst (DOC ref) and in the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst as obtained by XRF analysis.
Table 3. Content of Pd, Pt, S, P, and Ca in the fresh oxidation catalyst (DOC ref) and in the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst as obtained by XRF analysis.
SamplePd (wt.%)Pt (wt.%)S (wt.%)P (wt.%)Ca (ppm)
DOC ref0.49 ± 0.050.20 ± 0.050.00 ± 0.040.00 ± 0.04280 ± 70
DOC in0.64 ± 0.050.24 ± 0.050.27 ± 0.040.18 ± 0.04470 ± 70
DOC out0.69 ± 0.050.27 ± 0.050.25 ± 0.040.04 ± 0.04320 ± 70
Table
Table 4. Average Pd/Pt metal particle size, particle size distribution, and CO uptake for the fresh oxidation catalyst (DOC ref) and for the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst as obtained by TEM and CO chemisorption.
Table 4. Average Pd/Pt metal particle size, particle size distribution, and CO uptake for the fresh oxidation catalyst (DOC ref) and for the inlet (DOC in) and outlet (DOC out) of the engine bench aged oxidation catalyst as obtained by TEM and CO chemisorption.
SampleAverage Noble Metal Particle Size (nm)Particle Size Distribution (nm)CO Uptake (mol/mol Pd/Pt)
DOC ref4.02–90.063
DOC in9.55–170.001
DOC out8.02–190.003
Table
Table 5. Experimental protocol for oxidation activity tests. Base feed for all experiments: 8 vol.% O2, 5 vol% H2O, and Ar used as balance. GHSV: 45,000 h−1. The temperature was increased and decreased linearly by 5 °C/min.
Table 5. Experimental protocol for oxidation activity tests. Base feed for all experiments: 8 vol.% O2, 5 vol% H2O, and Ar used as balance. GHSV: 45,000 h−1. The temperature was increased and decreased linearly by 5 °C/min.
Temp (°C)CO (vol. ppm)CH4 (vol. ppm)NO (vol. ppm)Description
100–450↑↓1000--CO oxidation
100–450↑↓-1000-CH4 oxidation
100–450↑↓--1000NO oxidation
100–450↑↓100010001000Complex mixture of gases

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Englund, J.; Xie, K.; Dahlin, S.; Schaefer, A.; Jing, D.; Shwan, S.; Andersson, L.; Carlsson, P.-A.; Pettersson, L.J.; Skoglundh, M. Deactivation of a Pd/Pt Bimetallic Oxidation Catalyst Used in a Biogas-Powered Euro VI Heavy-Duty Engine Installation. Catalysts 2019, 9, 1014. https://0-doi-org.brum.beds.ac.uk/10.3390/catal9121014

AMA Style

Englund J, Xie K, Dahlin S, Schaefer A, Jing D, Shwan S, Andersson L, Carlsson P-A, Pettersson LJ, Skoglundh M. Deactivation of a Pd/Pt Bimetallic Oxidation Catalyst Used in a Biogas-Powered Euro VI Heavy-Duty Engine Installation. Catalysts. 2019; 9(12):1014. https://0-doi-org.brum.beds.ac.uk/10.3390/catal9121014

Chicago/Turabian Style

Englund, Johanna, Kunpeng Xie, Sandra Dahlin, Andreas Schaefer, Dazheng Jing, Soran Shwan, Lennart Andersson, Per-Anders Carlsson, Lars J. Pettersson, and Magnus Skoglundh. 2019. "Deactivation of a Pd/Pt Bimetallic Oxidation Catalyst Used in a Biogas-Powered Euro VI Heavy-Duty Engine Installation" Catalysts 9, no. 12: 1014. https://0-doi-org.brum.beds.ac.uk/10.3390/catal9121014

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