An 8 MeV Electron Beam Modified In:ZnO Thin Films for CO Gas Sensing towards Low Concentration
Abstract
:1. Introduction
2. Particulars of the Experiment
2.1. Synthesis of IZO Thin Films and Electron Beam Treatment
2.2. IZO Thin Film Characterization
2.3. Gas Sensing Tests
3. Results and Discussion
3.1. Structural Investigation
3.2. Morphological Properties
3.3. Photoluminescence Analysis
3.4. XPS Investigations
3.5. CO Sensing Studies
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Dosage | Crystalline Size, D (nm) | Dislocation Density, δ (1015 Lines m−2) | Strain, ε (10−3) |
---|---|---|---|
5 kGy | 18.87 | 2.82 | 1.84 |
10 kGy | 18.40 | 2.94 | 1.87 |
15 kGy | 18.97 | 2.81 | 1.83 |
15 wt% In Doped ZnO | ||||||
---|---|---|---|---|---|---|
Response Time (s) | Recovery Time (s) | |||||
Irradiation Dosage (kGy)/Gas Conc. (ppm) | 5 | 10 | 15 | 5 | 10 | 15 |
1 | 74 | 15 | 106 | 240 | 29 | 57 |
2 | 48 | 25 | 100 | 161 | 80 | 93 |
3 | 54 | 66 | 108 | 116 | 68 | 100 |
4 | 39 | 46 | 102 | 79 | 53 | 83 |
5 | 32 | 52 | 82 | 61 | 43 | 91 |
Irradiation Dosage (kGy)/Gas Conc. (ppm) | Sensor Response (15 wt% In Doped ZnO) (Response ±0.10) | ||
---|---|---|---|
5 | 10 | 15 | |
1 | 1.46 | 2.61 | - |
2 | 2.50 | 3.22 | 0.20 |
3 | 3.26 | 4.18 | 0.37 |
4 | 3.64 | 4.22 | 0.47 |
5 | 3.87 | 4.35 | 0.60 |
Material | Preparation Method | Conc. (ppm) | Operating Temperature | Sensor Response | Reference |
---|---|---|---|---|---|
Electron beam irradiated (10 kGy) IZO thin films | Spray Pyrolysis | 5 (LDL:1 ppm) | 300 °C | 4.35 (2.61 (1 ppm)) | This work |
In:ZnO nanoparticles | sol-gel | 50 (LDL:5) | 300 °C | 4.80 | [46] |
In:ZnO nanoparticles | Sol-gel | 50 (LDL:5) | 300 °C | 3.5 | [47] |
Cu:ZnO | Co-sputtering | 20 | 350 °C | 2.7 | [48] |
Al:ZnO nanoparticles | Sol-gel | 50 (LDL:5) | 300 °C | 1.6 | [7] |
ZnO:rGO nanoparticles | hydrothermal | 1000 | 200 °C | 7 | [49] |
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Ani, A.; Poornesh, P.; Antony, A.; Nagaraja, K.K.; Rao, A.; Hegde, G.; Kolesnikov, E.; Shchetinin, I.V.; Kulkarni, S.D.; Petwal, V.C.; et al. An 8 MeV Electron Beam Modified In:ZnO Thin Films for CO Gas Sensing towards Low Concentration. Nanomaterials 2021, 11, 3151. https://0-doi-org.brum.beds.ac.uk/10.3390/nano11113151
Ani A, Poornesh P, Antony A, Nagaraja KK, Rao A, Hegde G, Kolesnikov E, Shchetinin IV, Kulkarni SD, Petwal VC, et al. An 8 MeV Electron Beam Modified In:ZnO Thin Films for CO Gas Sensing towards Low Concentration. Nanomaterials. 2021; 11(11):3151. https://0-doi-org.brum.beds.ac.uk/10.3390/nano11113151
Chicago/Turabian StyleAni, Aninamol, P. Poornesh, Albin Antony, K. K. Nagaraja, Ashok Rao, Gopalkrishna Hegde, Evgeny Kolesnikov, Igor V. Shchetinin, Suresh D. Kulkarni, Vikash Chandra Petwal, and et al. 2021. "An 8 MeV Electron Beam Modified In:ZnO Thin Films for CO Gas Sensing towards Low Concentration" Nanomaterials 11, no. 11: 3151. https://0-doi-org.brum.beds.ac.uk/10.3390/nano11113151