Controlling the Deposition Process of Nanoarchitectonic Nanocomposites Based on {Nb6−xTaxXi12}n+ Octahedral Cluster-Based Building Blocks (Xi = Cl, Br; 0 ≤ x ≤ 6, n = 2, 3, 4) for UV-NIR Blockers Coating Applications
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Study of the Powders and Solutions
3.2. Study of the {Nb6-xTaxXi12}@SiO2-PEG Films
3.3. Study of the {Nb6-xTaxXi12}-Y@PVP Films
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compositions of the Cluster Core in PVP | TL | TE | TL/TE | x | y | z | SNIR (%) |
---|---|---|---|---|---|---|---|
{Nb6Cli12}-12(VEC = 16) [30] | 62.2 | 48.3 | 1.29 | 0.38 | 0.43 | 0.19 | 53.7 |
{Nb6Cli12}-10(VEC = 15) | 57.1 | 58.2 | 0.98 | 0.42 | 0.47 | 0.11 | 32.0 |
{Nb5TaCli12}-16(VEC = 16) [31] | 54.1 | 40.7 | 1.33 | 0.37 | 0.43 | 0.20 | 54.4 |
{Nb4Ta2Cli12}-16(VEC = 16) | 58.1 | 46.2 | 1.26 | 0.34 | 0.41 | 0.26 | 46.2 |
{Nb3Ta3Cli12}-16(VEC = 16) | 61.5 | 50.8 | 1.21 | 0.33 | 0.39 | 0.27 | 40.2 |
{Nb2Ta4Cli12}-12(VEC = 16) | 60.6 | 57.1 | 1.06 | 0.28 | 0.36 | 0.36 | 29.3 |
{NbTa5Cli12}-12(VEC = 16) | 52.6 | 52.7 | 1.00 | 0.26 | 0.36 | 0.38 | 28.6 |
{Ta6Cli12}-10(VEC = 16) | 55.6 | 52.7 | 1.05 | 0.27 | 0.37 | 0.36 | 30.7 |
{Nb6Bri12}-12(VEC = 16) | 48.8 | 37.6 | 1.29 | 0.45 | 0.49 | 0.10 | 58.6 |
{Nb5TaBri12}-12(VEC = 16) [31] | 52.7 | 40.4 | 1.30 | 0.38 | 0.46 | 0.17 | 47.6 |
{Nb4Ta2Bri12}-8(VEC = 16) | 58.6 | 47.5 | 1.23 | 0.34 | 0.42 | 0.24 | 33.1 |
{Nb3Ta3Bri12}-12(VEC = 16) | 53.9 | 45.6 | 1.18 | 0.34 | 0.43 | 0.24 | 40.8 |
{Nb2Ta4Bri12}-8(VEC = 16) | 55.0 | 49.8 | 1.10 | 0.31 | 0.41 | 0.29 | 33.0 |
{NbTa5Bri12}-12(VEC = 16) | 50.2 | 45.5 | 1.10 | 0.32 | 0.42 | 0.26 | 35.2 |
{Ta6Bri12}-12(VEC = 16) | 55.7 | 58.1 | 0.95 | 0.28 | 0.42 | 0.30 | 18.4 |
{Ta6Bri12}-10(VEC = 15) | 71.2 | 56.1 | 1.27 | 0.37 | 0.42 | 0.21 | 35.8 |
@PVP on glass | 91.4 | 90.5 | 1.01 | 0.31 | 0.33 | 0.35 | 8.3 |
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Lebastard, C.; Wilmet, M.; Cordier, S.; Comby-Zerbino, C.; MacAleese, L.; Dugourd, P.; Hara, T.; Ohashi, N.; Uchikoshi, T.; Grasset, F. Controlling the Deposition Process of Nanoarchitectonic Nanocomposites Based on {Nb6−xTaxXi12}n+ Octahedral Cluster-Based Building Blocks (Xi = Cl, Br; 0 ≤ x ≤ 6, n = 2, 3, 4) for UV-NIR Blockers Coating Applications. Nanomaterials 2022, 12, 2052. https://0-doi-org.brum.beds.ac.uk/10.3390/nano12122052
Lebastard C, Wilmet M, Cordier S, Comby-Zerbino C, MacAleese L, Dugourd P, Hara T, Ohashi N, Uchikoshi T, Grasset F. Controlling the Deposition Process of Nanoarchitectonic Nanocomposites Based on {Nb6−xTaxXi12}n+ Octahedral Cluster-Based Building Blocks (Xi = Cl, Br; 0 ≤ x ≤ 6, n = 2, 3, 4) for UV-NIR Blockers Coating Applications. Nanomaterials. 2022; 12(12):2052. https://0-doi-org.brum.beds.ac.uk/10.3390/nano12122052
Chicago/Turabian StyleLebastard, Clément, Maxence Wilmet, Stéphane Cordier, Clothilde Comby-Zerbino, Luke MacAleese, Philippe Dugourd, Toru Hara, Naoki Ohashi, Tetsuo Uchikoshi, and Fabien Grasset. 2022. "Controlling the Deposition Process of Nanoarchitectonic Nanocomposites Based on {Nb6−xTaxXi12}n+ Octahedral Cluster-Based Building Blocks (Xi = Cl, Br; 0 ≤ x ≤ 6, n = 2, 3, 4) for UV-NIR Blockers Coating Applications" Nanomaterials 12, no. 12: 2052. https://0-doi-org.brum.beds.ac.uk/10.3390/nano12122052