Kinetics and Chemorheological Analysis of Cross-Linking Reactions in Humins
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Differential Scanning Calorimetry (DSC)
2.3. Rheology
2.4. Thermogravimetric Analysis (TGA)
2.5. Theoretical Calculation
2.6. Isoconversional Method
3. Results and Discussion
3.1. Isothermal Investigation
3.1.1. Analysis of the Cure Kinetics by Isothermal DSC Measurements
3.1.2. Analysis of the Cross-Linking Kinetics by Stochastically Temperature Modulated DSC Measurements
3.1.3. Relation between Extent of Cure (α) and Glass Transition Temperature (Tg)
3.2. Non-Isothermal Investigation
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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T (°C) | τ1 (min) | τ2 (min) | β1 | β2 |
---|---|---|---|---|
120 | 1.58 × 103 | 7.10 × 107 | 3.96 × 10−1 | 2.26 × 10−4 |
140 | 1.25 × 102 | 7.40 × 107 | 3.10 × 10−1 | 1.25 × 10−4 |
160 | 3.93 × 101 | 7.40 × 107 | 3.52 × 10−1 | 1.24 × 10−4 |
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Sangregorio, A.; Guigo, N.; Jong, E.d.; Sbirrazzuoli, N. Kinetics and Chemorheological Analysis of Cross-Linking Reactions in Humins. Polymers 2019, 11, 1804. https://0-doi-org.brum.beds.ac.uk/10.3390/polym11111804
Sangregorio A, Guigo N, Jong Ed, Sbirrazzuoli N. Kinetics and Chemorheological Analysis of Cross-Linking Reactions in Humins. Polymers. 2019; 11(11):1804. https://0-doi-org.brum.beds.ac.uk/10.3390/polym11111804
Chicago/Turabian StyleSangregorio, Anna, Nathanaël Guigo, Ed de Jong, and Nicolas Sbirrazzuoli. 2019. "Kinetics and Chemorheological Analysis of Cross-Linking Reactions in Humins" Polymers 11, no. 11: 1804. https://0-doi-org.brum.beds.ac.uk/10.3390/polym11111804